Cargando…
catena-Poly[[aquadipyridinecopper(II)]-μ-fumarato]
The title compound, [Cu(C(4)H(2)O(4))(C(5)H(5)N)(2)(H(2)O)](n), is a one-dimensional coordination polymer based on pyridine and fumarate ligands. Each Cu(II) cation is coordinated by two carboxylate O atoms belonging to two fumarate anions, two N atoms from two pyridine molecules and one water mol...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914965/ https://www.ncbi.nlm.nih.gov/pubmed/21200658 http://dx.doi.org/10.1107/S1600536807063738 |
_version_ | 1782184827415429120 |
---|---|
author | Xie, Dong Ye, Junwei Lin, Yuan Ning, Guiling |
author_facet | Xie, Dong Ye, Junwei Lin, Yuan Ning, Guiling |
author_sort | Xie, Dong |
collection | PubMed |
description | The title compound, [Cu(C(4)H(2)O(4))(C(5)H(5)N)(2)(H(2)O)](n), is a one-dimensional coordination polymer based on pyridine and fumarate ligands. Each Cu(II) cation is coordinated by two carboxylate O atoms belonging to two fumarate anions, two N atoms from two pyridine molecules and one water molecule, in a square-based pyramidal geometry. Each fumarate anion bridges two Cu(II) cations through the two carboxylate groups in a bis-monodentate fashion to form a one-dimensional polymeric chain along the c axis. Neighbouring chains are linked together to form a two-dimensional network parallel to the ac plane via hydrogen bonding interactions between uncoordinated carboxylate O atoms and coordinated water molecules of adjecent chains. |
format | Text |
id | pubmed-2914965 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29149652010-12-30 catena-Poly[[aquadipyridinecopper(II)]-μ-fumarato] Xie, Dong Ye, Junwei Lin, Yuan Ning, Guiling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(4)H(2)O(4))(C(5)H(5)N)(2)(H(2)O)](n), is a one-dimensional coordination polymer based on pyridine and fumarate ligands. Each Cu(II) cation is coordinated by two carboxylate O atoms belonging to two fumarate anions, two N atoms from two pyridine molecules and one water molecule, in a square-based pyramidal geometry. Each fumarate anion bridges two Cu(II) cations through the two carboxylate groups in a bis-monodentate fashion to form a one-dimensional polymeric chain along the c axis. Neighbouring chains are linked together to form a two-dimensional network parallel to the ac plane via hydrogen bonding interactions between uncoordinated carboxylate O atoms and coordinated water molecules of adjecent chains. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914965/ /pubmed/21200658 http://dx.doi.org/10.1107/S1600536807063738 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Xie, Dong Ye, Junwei Lin, Yuan Ning, Guiling catena-Poly[[aquadipyridinecopper(II)]-μ-fumarato] |
title |
catena-Poly[[aquadipyridinecopper(II)]-μ-fumarato] |
title_full |
catena-Poly[[aquadipyridinecopper(II)]-μ-fumarato] |
title_fullStr |
catena-Poly[[aquadipyridinecopper(II)]-μ-fumarato] |
title_full_unstemmed |
catena-Poly[[aquadipyridinecopper(II)]-μ-fumarato] |
title_short |
catena-Poly[[aquadipyridinecopper(II)]-μ-fumarato] |
title_sort | catena-poly[[aquadipyridinecopper(ii)]-μ-fumarato] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914965/ https://www.ncbi.nlm.nih.gov/pubmed/21200658 http://dx.doi.org/10.1107/S1600536807063738 |
work_keys_str_mv | AT xiedong catenapolyaquadipyridinecopperiimfumarato AT yejunwei catenapolyaquadipyridinecopperiimfumarato AT linyuan catenapolyaquadipyridinecopperiimfumarato AT ningguiling catenapolyaquadipyridinecopperiimfumarato |