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catena-Poly[[aqua­dipyridine­copper(II)]-μ-fumarato]

The title compound, [Cu(C(4)H(2)O(4))(C(5)H(5)N)(2)(H(2)O)](n), is a one-dimensional coordination polymer based on pyridine and fumarate ligands. Each Cu(II) cation is coordinated by two carboxyl­ate O atoms belonging to two fumarate anions, two N atoms from two pyridine mol­ecules and one water mol...

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Detalles Bibliográficos
Autores principales: Xie, Dong, Ye, Junwei, Lin, Yuan, Ning, Guiling
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914965/
https://www.ncbi.nlm.nih.gov/pubmed/21200658
http://dx.doi.org/10.1107/S1600536807063738
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author Xie, Dong
Ye, Junwei
Lin, Yuan
Ning, Guiling
author_facet Xie, Dong
Ye, Junwei
Lin, Yuan
Ning, Guiling
author_sort Xie, Dong
collection PubMed
description The title compound, [Cu(C(4)H(2)O(4))(C(5)H(5)N)(2)(H(2)O)](n), is a one-dimensional coordination polymer based on pyridine and fumarate ligands. Each Cu(II) cation is coordinated by two carboxyl­ate O atoms belonging to two fumarate anions, two N atoms from two pyridine mol­ecules and one water mol­ecule, in a square-based pyramidal geometry. Each fumarate anion bridges two Cu(II) cations through the two carboxyl­ate groups in a bis-monodentate fashion to form a one-dimensional polymeric chain along the c axis. Neighbouring chains are linked together to form a two-dimensional network parallel to the ac plane via hydrogen bonding inter­actions between uncoordinated carboxyl­ate O atoms and coordinated water mol­ecules of adjecent chains.
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spelling pubmed-29149652010-12-30 catena-Poly[[aqua­dipyridine­copper(II)]-μ-fumarato] Xie, Dong Ye, Junwei Lin, Yuan Ning, Guiling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(4)H(2)O(4))(C(5)H(5)N)(2)(H(2)O)](n), is a one-dimensional coordination polymer based on pyridine and fumarate ligands. Each Cu(II) cation is coordinated by two carboxyl­ate O atoms belonging to two fumarate anions, two N atoms from two pyridine mol­ecules and one water mol­ecule, in a square-based pyramidal geometry. Each fumarate anion bridges two Cu(II) cations through the two carboxyl­ate groups in a bis-monodentate fashion to form a one-dimensional polymeric chain along the c axis. Neighbouring chains are linked together to form a two-dimensional network parallel to the ac plane via hydrogen bonding inter­actions between uncoordinated carboxyl­ate O atoms and coordinated water mol­ecules of adjecent chains. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914965/ /pubmed/21200658 http://dx.doi.org/10.1107/S1600536807063738 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Xie, Dong
Ye, Junwei
Lin, Yuan
Ning, Guiling
catena-Poly[[aqua­dipyridine­copper(II)]-μ-fumarato]
title catena-Poly[[aqua­dipyridine­copper(II)]-μ-fumarato]
title_full catena-Poly[[aqua­dipyridine­copper(II)]-μ-fumarato]
title_fullStr catena-Poly[[aqua­dipyridine­copper(II)]-μ-fumarato]
title_full_unstemmed catena-Poly[[aqua­dipyridine­copper(II)]-μ-fumarato]
title_short catena-Poly[[aqua­dipyridine­copper(II)]-μ-fumarato]
title_sort catena-poly[[aqua­dipyridine­copper(ii)]-μ-fumarato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914965/
https://www.ncbi.nlm.nih.gov/pubmed/21200658
http://dx.doi.org/10.1107/S1600536807063738
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