Sodium (1R,2S,5S)-2-hydr­oxy-6,6-dimethyl­bicyclo­[3.1.1]heptane-2-carboxyl­ate penta­hydrate

In the title compound, Na(+)·C(10)H(15)O(3) (−)·5H(2)O, the vertices of a distorted octa­hedron centred on the Na(+) cation are defined by six O atoms of water mol­ecules. The edge-sharing Na(H(2)O)(6) octa­hedra form a chain extended along the b-axis direction with adjacent Na(+) cations related by...

Descripción completa

Detalles Bibliográficos
Autores principales: Ma, Shi-Ying, Zheng, Ze-Bao, Li, Ji-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914966/
https://www.ncbi.nlm.nih.gov/pubmed/21200659
http://dx.doi.org/10.1107/S1600536807063775
_version_ 1782184827650310144
author Ma, Shi-Ying
Zheng, Ze-Bao
Li, Ji-Kun
author_facet Ma, Shi-Ying
Zheng, Ze-Bao
Li, Ji-Kun
author_sort Ma, Shi-Ying
collection PubMed
description In the title compound, Na(+)·C(10)H(15)O(3) (−)·5H(2)O, the vertices of a distorted octa­hedron centred on the Na(+) cation are defined by six O atoms of water mol­ecules. The edge-sharing Na(H(2)O)(6) octa­hedra form a chain extended along the b-axis direction with adjacent Na(+) cations related by a twofold screw symmetry operation. The organic anion, which is not in close contact with the Na(+ )cation, is hydrogen-bonded to an uncoordinated water mol­ecule and to water mol­ecules of the Na(H(2)O)(6) octa­hedra.
format Text
id pubmed-2914966
institution National Center for Biotechnology Information
language English
publishDate 2007
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29149662010-12-30 Sodium (1R,2S,5S)-2-hydr­oxy-6,6-dimethyl­bicyclo­[3.1.1]heptane-2-carboxyl­ate penta­hydrate Ma, Shi-Ying Zheng, Ze-Bao Li, Ji-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, Na(+)·C(10)H(15)O(3) (−)·5H(2)O, the vertices of a distorted octa­hedron centred on the Na(+) cation are defined by six O atoms of water mol­ecules. The edge-sharing Na(H(2)O)(6) octa­hedra form a chain extended along the b-axis direction with adjacent Na(+) cations related by a twofold screw symmetry operation. The organic anion, which is not in close contact with the Na(+ )cation, is hydrogen-bonded to an uncoordinated water mol­ecule and to water mol­ecules of the Na(H(2)O)(6) octa­hedra. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914966/ /pubmed/21200659 http://dx.doi.org/10.1107/S1600536807063775 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Ma, Shi-Ying
Zheng, Ze-Bao
Li, Ji-Kun
Sodium (1R,2S,5S)-2-hydr­oxy-6,6-dimethyl­bicyclo­[3.1.1]heptane-2-carboxyl­ate penta­hydrate
title Sodium (1R,2S,5S)-2-hydr­oxy-6,6-dimethyl­bicyclo­[3.1.1]heptane-2-carboxyl­ate penta­hydrate
title_full Sodium (1R,2S,5S)-2-hydr­oxy-6,6-dimethyl­bicyclo­[3.1.1]heptane-2-carboxyl­ate penta­hydrate
title_fullStr Sodium (1R,2S,5S)-2-hydr­oxy-6,6-dimethyl­bicyclo­[3.1.1]heptane-2-carboxyl­ate penta­hydrate
title_full_unstemmed Sodium (1R,2S,5S)-2-hydr­oxy-6,6-dimethyl­bicyclo­[3.1.1]heptane-2-carboxyl­ate penta­hydrate
title_short Sodium (1R,2S,5S)-2-hydr­oxy-6,6-dimethyl­bicyclo­[3.1.1]heptane-2-carboxyl­ate penta­hydrate
title_sort sodium (1r,2s,5s)-2-hydr­oxy-6,6-dimethyl­bicyclo­[3.1.1]heptane-2-carboxyl­ate penta­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914966/
https://www.ncbi.nlm.nih.gov/pubmed/21200659
http://dx.doi.org/10.1107/S1600536807063775
work_keys_str_mv AT mashiying sodium1r2s5s2hydroxy66dimethylbicyclo311heptane2carboxylatepentahydrate
AT zhengzebao sodium1r2s5s2hydroxy66dimethylbicyclo311heptane2carboxylatepentahydrate
AT lijikun sodium1r2s5s2hydroxy66dimethylbicyclo311heptane2carboxylatepentahydrate

Ejemplares similares