Cargando…

Hexaaqua­cadmium(II) bis­{[N-(2-oxidobenzyl­idene)glycyl-l-leucinato]cuprate(II)} dihydrate

The title compound, [Cd(H(2)O)(6)][Cu(C(15)H(17)N(2)O(4))](2)·2H(2)O, has a chiral structure. Copper has a square-planar coordination with two N and two O atoms of the quadridentate chiral Schiff base ligand. The Cd(2+) ion is coordinated by six aqua ligands with a slightly distorted octa­hedral con...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Guolin, Ye, Lihua, Zhang, Yanyan, Liu, Wenlong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914968/
https://www.ncbi.nlm.nih.gov/pubmed/21200661
http://dx.doi.org/10.1107/S1600536807063635
Descripción
Sumario:The title compound, [Cd(H(2)O)(6)][Cu(C(15)H(17)N(2)O(4))](2)·2H(2)O, has a chiral structure. Copper has a square-planar coordination with two N and two O atoms of the quadridentate chiral Schiff base ligand. The Cd(2+) ion is coordinated by six aqua ligands with a slightly distorted octa­hedral configuration. Ions are linked by O—H⋯O hydrogen bonds, and the [Cd(H(2)O)(6)](2+) cations and [CuL](−) anions (L = Schiff base derived from glycyl-l-leucine and salicylaldehyde) occupy a stacking structure within well separated columns along the a axis. The two crystallographically independent copper–Schiff base anions each have a chiral carbon centre with an S configuration. They are related by a non-crystallographic twofold rotation axis parallel to the [010] direction.