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Hexaaquacadmium(II) bis{[N-(2-oxidobenzylidene)glycyl-l-leucinato]cuprate(II)} dihydrate
The title compound, [Cd(H(2)O)(6)][Cu(C(15)H(17)N(2)O(4))](2)·2H(2)O, has a chiral structure. Copper has a square-planar coordination with two N and two O atoms of the quadridentate chiral Schiff base ligand. The Cd(2+) ion is coordinated by six aqua ligands with a slightly distorted octahedral con...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914968/ https://www.ncbi.nlm.nih.gov/pubmed/21200661 http://dx.doi.org/10.1107/S1600536807063635 |
Sumario: | The title compound, [Cd(H(2)O)(6)][Cu(C(15)H(17)N(2)O(4))](2)·2H(2)O, has a chiral structure. Copper has a square-planar coordination with two N and two O atoms of the quadridentate chiral Schiff base ligand. The Cd(2+) ion is coordinated by six aqua ligands with a slightly distorted octahedral configuration. Ions are linked by O—H⋯O hydrogen bonds, and the [Cd(H(2)O)(6)](2+) cations and [CuL](−) anions (L = Schiff base derived from glycyl-l-leucine and salicylaldehyde) occupy a stacking structure within well separated columns along the a axis. The two crystallographically independent copper–Schiff base anions each have a chiral carbon centre with an S configuration. They are related by a non-crystallographic twofold rotation axis parallel to the [010] direction. |
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