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Bis[μ-4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]bis{bis[4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]nickel(II)} tetranitrate methanol disolvate
The title complex, [Ni(2)(C(4)H(8)N(4)O(2))(6)](NO(3))(4)·2CH(4)O, contains a centrosymmetric binuclear nickel(II) complex bridged by a pair of 4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole ligands. The separation between the Ni(II) atoms is 3.962 (1) Å. The Ni atoms are in a slightly distorted o...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2007
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914969/ https://www.ncbi.nlm.nih.gov/pubmed/21200662 http://dx.doi.org/10.1107/S1600536807064148 |
| _version_ | 1782184828345516032 |
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| author | Pan, Yu-Peng Li, Da-Cheng Wang, Da-Qi |
| author_facet | Pan, Yu-Peng Li, Da-Cheng Wang, Da-Qi |
| author_sort | Pan, Yu-Peng |
| collection | PubMed |
| description | The title complex, [Ni(2)(C(4)H(8)N(4)O(2))(6)](NO(3))(4)·2CH(4)O, contains a centrosymmetric binuclear nickel(II) complex bridged by a pair of 4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole ligands. The separation between the Ni(II) atoms is 3.962 (1) Å. The Ni atoms are in a slightly distorted octahedral coordination. Intermolecular N—H⋯O, N—H⋯N and O—H⋯O hydrogen bonds connect the ligands, solvent molecules and nitrate ions. |
| format | Text |
| id | pubmed-2914969 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2007 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29149692010-12-30 Bis[μ-4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]bis{bis[4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]nickel(II)} tetranitrate methanol disolvate Pan, Yu-Peng Li, Da-Cheng Wang, Da-Qi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Ni(2)(C(4)H(8)N(4)O(2))(6)](NO(3))(4)·2CH(4)O, contains a centrosymmetric binuclear nickel(II) complex bridged by a pair of 4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole ligands. The separation between the Ni(II) atoms is 3.962 (1) Å. The Ni atoms are in a slightly distorted octahedral coordination. Intermolecular N—H⋯O, N—H⋯N and O—H⋯O hydrogen bonds connect the ligands, solvent molecules and nitrate ions. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914969/ /pubmed/21200662 http://dx.doi.org/10.1107/S1600536807064148 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
| spellingShingle | Metal-Organic Papers Pan, Yu-Peng Li, Da-Cheng Wang, Da-Qi Bis[μ-4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]bis{bis[4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]nickel(II)} tetranitrate methanol disolvate |
| title | Bis[μ-4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]bis{bis[4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]nickel(II)} tetranitrate methanol disolvate |
| title_full | Bis[μ-4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]bis{bis[4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]nickel(II)} tetranitrate methanol disolvate |
| title_fullStr | Bis[μ-4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]bis{bis[4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]nickel(II)} tetranitrate methanol disolvate |
| title_full_unstemmed | Bis[μ-4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]bis{bis[4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]nickel(II)} tetranitrate methanol disolvate |
| title_short | Bis[μ-4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]bis{bis[4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]nickel(II)} tetranitrate methanol disolvate |
| title_sort | bis[μ-4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]bis{bis[4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole]nickel(ii)} tetranitrate methanol disolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914969/ https://www.ncbi.nlm.nih.gov/pubmed/21200662 http://dx.doi.org/10.1107/S1600536807064148 |
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