Tetra­kis(triphenyl­arsine)copper(I) hexa­fluoridophosphate

In the crystal structure of the title compound, [Cu(C(18)H(15)As)(4)]PF(6), the Cu atom is coordinated by four As atoms of triphenyl­arsine ligands in a tetra­hedral geometry. The complex cation is located on a crystallographic threefold axis. Both PF(6) (−) anions are located on special positions o...

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Detalles Bibliográficos
Autores principales: Kern, Thomas, Knör, Günther, Zabel, Manfred, Monkowius, Uwe
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914971/
https://www.ncbi.nlm.nih.gov/pubmed/21200664
http://dx.doi.org/10.1107/S1600536807064458
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author Kern, Thomas
Knör, Günther
Zabel, Manfred
Monkowius, Uwe
author_facet Kern, Thomas
Knör, Günther
Zabel, Manfred
Monkowius, Uwe
author_sort Kern, Thomas
collection PubMed
description In the crystal structure of the title compound, [Cu(C(18)H(15)As)(4)]PF(6), the Cu atom is coordinated by four As atoms of triphenyl­arsine ligands in a tetra­hedral geometry. The complex cation is located on a crystallographic threefold axis. Both PF(6) (−) anions are located on special positions of site symmetry [Image: see text]. The Cu—As bond of the independent arsine ligand is shorter than the Cu—As bonds of the three symmetry-related arsine ligands.
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spelling pubmed-29149712010-12-30 Tetra­kis(triphenyl­arsine)copper(I) hexa­fluoridophosphate Kern, Thomas Knör, Günther Zabel, Manfred Monkowius, Uwe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Cu(C(18)H(15)As)(4)]PF(6), the Cu atom is coordinated by four As atoms of triphenyl­arsine ligands in a tetra­hedral geometry. The complex cation is located on a crystallographic threefold axis. Both PF(6) (−) anions are located on special positions of site symmetry [Image: see text]. The Cu—As bond of the independent arsine ligand is shorter than the Cu—As bonds of the three symmetry-related arsine ligands. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914971/ /pubmed/21200664 http://dx.doi.org/10.1107/S1600536807064458 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Kern, Thomas
Knör, Günther
Zabel, Manfred
Monkowius, Uwe
Tetra­kis(triphenyl­arsine)copper(I) hexa­fluoridophosphate
title Tetra­kis(triphenyl­arsine)copper(I) hexa­fluoridophosphate
title_full Tetra­kis(triphenyl­arsine)copper(I) hexa­fluoridophosphate
title_fullStr Tetra­kis(triphenyl­arsine)copper(I) hexa­fluoridophosphate
title_full_unstemmed Tetra­kis(triphenyl­arsine)copper(I) hexa­fluoridophosphate
title_short Tetra­kis(triphenyl­arsine)copper(I) hexa­fluoridophosphate
title_sort tetra­kis(triphenyl­arsine)copper(i) hexa­fluoridophosphate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914971/
https://www.ncbi.nlm.nih.gov/pubmed/21200664
http://dx.doi.org/10.1107/S1600536807064458
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AT knorgunther tetrakistriphenylarsinecopperihexafluoridophosphate
AT zabelmanfred tetrakistriphenylarsinecopperihexafluoridophosphate
AT monkowiusuwe tetrakistriphenylarsinecopperihexafluoridophosphate

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