N-(3,4-Dimethyl­phen­yl)acetamide

The conformation of the N—H bond in the title compound (34DMPA), C(10)H(13)NO, is syn to the 3-methyl substituent in the aromatic ring, in contrast to the anti conformation observed with respect to the 3-chloro substituent in N-(3,4-dichloro­phen­yl)acetamide (34DCPA). The asymmetric unit of the str...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914973/
https://www.ncbi.nlm.nih.gov/pubmed/21200674
http://dx.doi.org/10.1107/S1600536807060916
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author Gowda, B. Thimme
Foro, Sabine
Fuess, Hartmut
author_facet Gowda, B. Thimme
Foro, Sabine
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description The conformation of the N—H bond in the title compound (34DMPA), C(10)H(13)NO, is syn to the 3-methyl substituent in the aromatic ring, in contrast to the anti conformation observed with respect to the 3-chloro substituent in N-(3,4-dichloro­phen­yl)acetamide (34DCPA). The asymmetric unit of the structure contains three mol­ecules. The bond parameters in 34DMPA are similar to those in 34DCPA, N-(2,6-dimethyl­phen­yl)acetamide, N-(3,5-dimethyl­phen­yl)acetamide and other acetanilides. The mol­ecules in 34DMPA are linked into infinite chains through N—H⋯O hydrogen bonding.
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spelling pubmed-29149732010-12-30 N-(3,4-Dimethyl­phen­yl)acetamide Gowda, B. Thimme Foro, Sabine Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers The conformation of the N—H bond in the title compound (34DMPA), C(10)H(13)NO, is syn to the 3-methyl substituent in the aromatic ring, in contrast to the anti conformation observed with respect to the 3-chloro substituent in N-(3,4-dichloro­phen­yl)acetamide (34DCPA). The asymmetric unit of the structure contains three mol­ecules. The bond parameters in 34DMPA are similar to those in 34DCPA, N-(2,6-dimethyl­phen­yl)acetamide, N-(3,5-dimethyl­phen­yl)acetamide and other acetanilides. The mol­ecules in 34DMPA are linked into infinite chains through N—H⋯O hydrogen bonding. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914973/ /pubmed/21200674 http://dx.doi.org/10.1107/S1600536807060916 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Gowda, B. Thimme
Foro, Sabine
Fuess, Hartmut
N-(3,4-Dimethyl­phen­yl)acetamide
title N-(3,4-Dimethyl­phen­yl)acetamide
title_full N-(3,4-Dimethyl­phen­yl)acetamide
title_fullStr N-(3,4-Dimethyl­phen­yl)acetamide
title_full_unstemmed N-(3,4-Dimethyl­phen­yl)acetamide
title_short N-(3,4-Dimethyl­phen­yl)acetamide
title_sort n-(3,4-dimethyl­phen­yl)acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914973/
https://www.ncbi.nlm.nih.gov/pubmed/21200674
http://dx.doi.org/10.1107/S1600536807060916
work_keys_str_mv AT gowdabthimme n34dimethylphenylacetamide
AT forosabine n34dimethylphenylacetamide
AT fuesshartmut n34dimethylphenylacetamide

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