Diethyl 5,5′-thio­bis[2-amino-4-(4-fluoro­phen­yl)-1-phenyl-1H-pyrrole-3-carboxyl­ate]

In the title compound, C(38)H(32)F(2)N(4)O(4)S, the ethyl chain of the ethoxy­carbonyl group displays rotational disorder with site occupancy factors ca 0.6 and 0.4. The S atom lies on a twofold rotation axis. There are both inter- and intra­molecular hydrogen bonds in the crystal structure. An intr...

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Detalles Bibliográficos
Autores principales: Li, Ming, Cao, Guo-Rui, Weng, Li-Rong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914983/
https://www.ncbi.nlm.nih.gov/pubmed/21200775
http://dx.doi.org/10.1107/S1600536807061545
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author Li, Ming
Cao, Guo-Rui
Weng, Li-Rong
author_facet Li, Ming
Cao, Guo-Rui
Weng, Li-Rong
author_sort Li, Ming
collection PubMed
description In the title compound, C(38)H(32)F(2)N(4)O(4)S, the ethyl chain of the ethoxy­carbonyl group displays rotational disorder with site occupancy factors ca 0.6 and 0.4. The S atom lies on a twofold rotation axis. There are both inter- and intra­molecular hydrogen bonds in the crystal structure. An intra­molecular N—H⋯O hydrogen bond forms a six-membered ring, while an inter­molecular N—H⋯F hydrogen bond results in a chain.
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spelling pubmed-29149832010-12-30 Diethyl 5,5′-thio­bis[2-amino-4-(4-fluoro­phen­yl)-1-phenyl-1H-pyrrole-3-carboxyl­ate] Li, Ming Cao, Guo-Rui Weng, Li-Rong Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(38)H(32)F(2)N(4)O(4)S, the ethyl chain of the ethoxy­carbonyl group displays rotational disorder with site occupancy factors ca 0.6 and 0.4. The S atom lies on a twofold rotation axis. There are both inter- and intra­molecular hydrogen bonds in the crystal structure. An intra­molecular N—H⋯O hydrogen bond forms a six-membered ring, while an inter­molecular N—H⋯F hydrogen bond results in a chain. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914983/ /pubmed/21200775 http://dx.doi.org/10.1107/S1600536807061545 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Li, Ming
Cao, Guo-Rui
Weng, Li-Rong
Diethyl 5,5′-thio­bis[2-amino-4-(4-fluoro­phen­yl)-1-phenyl-1H-pyrrole-3-carboxyl­ate]
title Diethyl 5,5′-thio­bis[2-amino-4-(4-fluoro­phen­yl)-1-phenyl-1H-pyrrole-3-carboxyl­ate]
title_full Diethyl 5,5′-thio­bis[2-amino-4-(4-fluoro­phen­yl)-1-phenyl-1H-pyrrole-3-carboxyl­ate]
title_fullStr Diethyl 5,5′-thio­bis[2-amino-4-(4-fluoro­phen­yl)-1-phenyl-1H-pyrrole-3-carboxyl­ate]
title_full_unstemmed Diethyl 5,5′-thio­bis[2-amino-4-(4-fluoro­phen­yl)-1-phenyl-1H-pyrrole-3-carboxyl­ate]
title_short Diethyl 5,5′-thio­bis[2-amino-4-(4-fluoro­phen­yl)-1-phenyl-1H-pyrrole-3-carboxyl­ate]
title_sort diethyl 5,5′-thio­bis[2-amino-4-(4-fluoro­phen­yl)-1-phenyl-1h-pyrrole-3-carboxyl­ate]
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914983/
https://www.ncbi.nlm.nih.gov/pubmed/21200775
http://dx.doi.org/10.1107/S1600536807061545
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