Ethyl 2-acetyl­hydrazono-2-phenyl­acetate

The title compound, C(12)H(14)N(2)O(3), was synthesized as an inter­mediate for the synthesis of metamitron. The benzene ring forms dihedral angles of 86.3 (2) and 10.0 (3)° with the ethyl group and the acetyl­imino plane, respectively. The crystal structure involves inter­molecular C—H⋯O and N—H⋯O...

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Autores principales: Xu, Liang-Zhong, Yi, Xu, An, Guang-Wei, Zhang, Gong-Sheng, Li, Chun-Fang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914993/
https://www.ncbi.nlm.nih.gov/pubmed/21200890
http://dx.doi.org/10.1107/S1600536807060941
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author Xu, Liang-Zhong
Yi, Xu
An, Guang-Wei
Zhang, Gong-Sheng
Li, Chun-Fang
author_facet Xu, Liang-Zhong
Yi, Xu
An, Guang-Wei
Zhang, Gong-Sheng
Li, Chun-Fang
author_sort Xu, Liang-Zhong
collection PubMed
description The title compound, C(12)H(14)N(2)O(3), was synthesized as an inter­mediate for the synthesis of metamitron. The benzene ring forms dihedral angles of 86.3 (2) and 10.0 (3)° with the ethyl group and the acetyl­imino plane, respectively. The crystal structure involves inter­molecular C—H⋯O and N—H⋯O hydrogen bonds.
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spelling pubmed-29149932010-12-30 Ethyl 2-acetyl­hydrazono-2-phenyl­acetate Xu, Liang-Zhong Yi, Xu An, Guang-Wei Zhang, Gong-Sheng Li, Chun-Fang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(12)H(14)N(2)O(3), was synthesized as an inter­mediate for the synthesis of metamitron. The benzene ring forms dihedral angles of 86.3 (2) and 10.0 (3)° with the ethyl group and the acetyl­imino plane, respectively. The crystal structure involves inter­molecular C—H⋯O and N—H⋯O hydrogen bonds. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2914993/ /pubmed/21200890 http://dx.doi.org/10.1107/S1600536807060941 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Xu, Liang-Zhong
Yi, Xu
An, Guang-Wei
Zhang, Gong-Sheng
Li, Chun-Fang
Ethyl 2-acetyl­hydrazono-2-phenyl­acetate
title Ethyl 2-acetyl­hydrazono-2-phenyl­acetate
title_full Ethyl 2-acetyl­hydrazono-2-phenyl­acetate
title_fullStr Ethyl 2-acetyl­hydrazono-2-phenyl­acetate
title_full_unstemmed Ethyl 2-acetyl­hydrazono-2-phenyl­acetate
title_short Ethyl 2-acetyl­hydrazono-2-phenyl­acetate
title_sort ethyl 2-acetyl­hydrazono-2-phenyl­acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2914993/
https://www.ncbi.nlm.nih.gov/pubmed/21200890
http://dx.doi.org/10.1107/S1600536807060941
work_keys_str_mv AT xuliangzhong ethyl2acetylhydrazono2phenylacetate
AT yixu ethyl2acetylhydrazono2phenylacetate
AT anguangwei ethyl2acetylhydrazono2phenylacetate
AT zhanggongsheng ethyl2acetylhydrazono2phenylacetate
AT lichunfang ethyl2acetylhydrazono2phenylacetate

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