N-(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)-4-methyl­benzene­sulfonamide

In the title compound, C(18)H(19)N(3)O(3)S, the phenyl ring and the pyrazole ring are twisted with respect to each other by an angle of 49.11 (7)°. The C—N—S—C torsion angle is −122.5 (2)°. The methyl group bonded to the N atom of the pyrazole ring has a large deviation from the mean ring plane of 0...

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Detalles Bibliográficos
Autores principales: da Silva, Luiz Everson, de Sousa Jr, Paulo Teixeira, Dall’Oglio, Evandro Luiz, Foro, Sabine
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915010/
https://www.ncbi.nlm.nih.gov/pubmed/21200928
http://dx.doi.org/10.1107/S1600536807061594
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author da Silva, Luiz Everson
de Sousa Jr, Paulo Teixeira
Dall’Oglio, Evandro Luiz
Foro, Sabine
author_facet da Silva, Luiz Everson
de Sousa Jr, Paulo Teixeira
Dall’Oglio, Evandro Luiz
Foro, Sabine
author_sort da Silva, Luiz Everson
collection PubMed
description In the title compound, C(18)H(19)N(3)O(3)S, the phenyl ring and the pyrazole ring are twisted with respect to each other by an angle of 49.11 (7)°. The C—N—S—C torsion angle is −122.5 (2)°. The methyl group bonded to the N atom of the pyrazole ring has a large deviation from the mean ring plane of 0.603 (3) Å. One inter­molecular N—H⋯O and two non-classical inter­molecular C—H⋯O hydrogen bonds are observed in the crystal structure.
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spelling pubmed-29150102010-12-30 N-(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)-4-methyl­benzene­sulfonamide da Silva, Luiz Everson de Sousa Jr, Paulo Teixeira Dall’Oglio, Evandro Luiz Foro, Sabine Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(19)N(3)O(3)S, the phenyl ring and the pyrazole ring are twisted with respect to each other by an angle of 49.11 (7)°. The C—N—S—C torsion angle is −122.5 (2)°. The methyl group bonded to the N atom of the pyrazole ring has a large deviation from the mean ring plane of 0.603 (3) Å. One inter­molecular N—H⋯O and two non-classical inter­molecular C—H⋯O hydrogen bonds are observed in the crystal structure. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915010/ /pubmed/21200928 http://dx.doi.org/10.1107/S1600536807061594 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
da Silva, Luiz Everson
de Sousa Jr, Paulo Teixeira
Dall’Oglio, Evandro Luiz
Foro, Sabine
N-(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)-4-methyl­benzene­sulfonamide
title N-(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)-4-methyl­benzene­sulfonamide
title_full N-(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)-4-methyl­benzene­sulfonamide
title_fullStr N-(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)-4-methyl­benzene­sulfonamide
title_full_unstemmed N-(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)-4-methyl­benzene­sulfonamide
title_short N-(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)-4-methyl­benzene­sulfonamide
title_sort n-(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1h-pyrazol-4-yl)-4-methyl­benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915010/
https://www.ncbi.nlm.nih.gov/pubmed/21200928
http://dx.doi.org/10.1107/S1600536807061594
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