(E)-Methyl 3-(2-nitro­benzyl­idene)dithio­carbazate

The asymmetric unit of the title compound, C(9)H(9)N(3)O(2)S(2), contains two independent mol­ecules, A and B, with similar bond dimensions. In both mol­ecules, the nitro group is tilted with respect to the aromatic ring [dihedral angles 32.0 (1)° in mol­ecule A and 34.0 (1)° in mol­ecule B]. The di...

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Detalles Bibliográficos
Autores principales: Shan, Shang, Tian, Yu-Liang, Wang, Wen-Long, Wang, Shan-Heng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915011/
https://www.ncbi.nlm.nih.gov/pubmed/21200929
http://dx.doi.org/10.1107/S160053680706059X
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author Shan, Shang
Tian, Yu-Liang
Wang, Wen-Long
Wang, Shan-Heng
author_facet Shan, Shang
Tian, Yu-Liang
Wang, Wen-Long
Wang, Shan-Heng
author_sort Shan, Shang
collection PubMed
description The asymmetric unit of the title compound, C(9)H(9)N(3)O(2)S(2), contains two independent mol­ecules, A and B, with similar bond dimensions. In both mol­ecules, the nitro group is tilted with respect to the aromatic ring [dihedral angles 32.0 (1)° in mol­ecule A and 34.0 (1)° in mol­ecule B]. The dithio­carbazate unit is nearly coplanar with the aromatic ring in both mol­ecules. For mol­ecule B, pairs of mol­ecules are linked by N—H⋯O and C—H⋯O hydrogen bonds about a centre of symmetry to form a dimer, whereas mol­ecules A are not involved in hydrogen bonding in the crystal structure.
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spelling pubmed-29150112010-12-30 (E)-Methyl 3-(2-nitro­benzyl­idene)dithio­carbazate Shan, Shang Tian, Yu-Liang Wang, Wen-Long Wang, Shan-Heng Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(9)H(9)N(3)O(2)S(2), contains two independent mol­ecules, A and B, with similar bond dimensions. In both mol­ecules, the nitro group is tilted with respect to the aromatic ring [dihedral angles 32.0 (1)° in mol­ecule A and 34.0 (1)° in mol­ecule B]. The dithio­carbazate unit is nearly coplanar with the aromatic ring in both mol­ecules. For mol­ecule B, pairs of mol­ecules are linked by N—H⋯O and C—H⋯O hydrogen bonds about a centre of symmetry to form a dimer, whereas mol­ecules A are not involved in hydrogen bonding in the crystal structure. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915011/ /pubmed/21200929 http://dx.doi.org/10.1107/S160053680706059X Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Shan, Shang
Tian, Yu-Liang
Wang, Wen-Long
Wang, Shan-Heng
(E)-Methyl 3-(2-nitro­benzyl­idene)dithio­carbazate
title (E)-Methyl 3-(2-nitro­benzyl­idene)dithio­carbazate
title_full (E)-Methyl 3-(2-nitro­benzyl­idene)dithio­carbazate
title_fullStr (E)-Methyl 3-(2-nitro­benzyl­idene)dithio­carbazate
title_full_unstemmed (E)-Methyl 3-(2-nitro­benzyl­idene)dithio­carbazate
title_short (E)-Methyl 3-(2-nitro­benzyl­idene)dithio­carbazate
title_sort (e)-methyl 3-(2-nitro­benzyl­idene)dithio­carbazate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915011/
https://www.ncbi.nlm.nih.gov/pubmed/21200929
http://dx.doi.org/10.1107/S160053680706059X
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AT wangshanheng emethyl32nitrobenzylidenedithiocarbazate

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