(1R,4R,7S)-1,7-Dimethyl-7-(phenyl­sulfonyl­meth­yl)spiro­[bicyclo­[2.2.1]heptane-2,2′-1,3-dioxolane]

In the title compound, C(18)H(24)O(4)S, the chiral bicyclo­[2.2.1]heptane group is not symmetrical due to the influence of the substituents. The angle between the three-atom bridge plane and the four-atom planes of the boat-shaped six-membered ring are 55.07 (19) and 56.24 (19)°. The bridgehead angl...

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Detalles Bibliográficos
Autores principales: Wang, Ya-Wen, Peng, Yu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915015/
https://www.ncbi.nlm.nih.gov/pubmed/21200933
http://dx.doi.org/10.1107/S1600536807058084
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author Wang, Ya-Wen
Peng, Yu
author_facet Wang, Ya-Wen
Peng, Yu
author_sort Wang, Ya-Wen
collection PubMed
description In the title compound, C(18)H(24)O(4)S, the chiral bicyclo­[2.2.1]heptane group is not symmetrical due to the influence of the substituents. The angle between the three-atom bridge plane and the four-atom planes of the boat-shaped six-membered ring are 55.07 (19) and 56.24 (19)°. The bridgehead angle is 92.75 (17)°.
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spelling pubmed-29150152010-12-30 (1R,4R,7S)-1,7-Dimethyl-7-(phenyl­sulfonyl­meth­yl)spiro­[bicyclo­[2.2.1]heptane-2,2′-1,3-dioxolane] Wang, Ya-Wen Peng, Yu Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(24)O(4)S, the chiral bicyclo­[2.2.1]heptane group is not symmetrical due to the influence of the substituents. The angle between the three-atom bridge plane and the four-atom planes of the boat-shaped six-membered ring are 55.07 (19) and 56.24 (19)°. The bridgehead angle is 92.75 (17)°. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915015/ /pubmed/21200933 http://dx.doi.org/10.1107/S1600536807058084 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Wang, Ya-Wen
Peng, Yu
(1R,4R,7S)-1,7-Dimethyl-7-(phenyl­sulfonyl­meth­yl)spiro­[bicyclo­[2.2.1]heptane-2,2′-1,3-dioxolane]
title (1R,4R,7S)-1,7-Dimethyl-7-(phenyl­sulfonyl­meth­yl)spiro­[bicyclo­[2.2.1]heptane-2,2′-1,3-dioxolane]
title_full (1R,4R,7S)-1,7-Dimethyl-7-(phenyl­sulfonyl­meth­yl)spiro­[bicyclo­[2.2.1]heptane-2,2′-1,3-dioxolane]
title_fullStr (1R,4R,7S)-1,7-Dimethyl-7-(phenyl­sulfonyl­meth­yl)spiro­[bicyclo­[2.2.1]heptane-2,2′-1,3-dioxolane]
title_full_unstemmed (1R,4R,7S)-1,7-Dimethyl-7-(phenyl­sulfonyl­meth­yl)spiro­[bicyclo­[2.2.1]heptane-2,2′-1,3-dioxolane]
title_short (1R,4R,7S)-1,7-Dimethyl-7-(phenyl­sulfonyl­meth­yl)spiro­[bicyclo­[2.2.1]heptane-2,2′-1,3-dioxolane]
title_sort (1r,4r,7s)-1,7-dimethyl-7-(phenyl­sulfonyl­meth­yl)spiro­[bicyclo­[2.2.1]heptane-2,2′-1,3-dioxolane]
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915015/
https://www.ncbi.nlm.nih.gov/pubmed/21200933
http://dx.doi.org/10.1107/S1600536807058084
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AT pengyu 1r4r7s17dimethyl7phenylsulfonylmethylspirobicyclo221heptane2213dioxolane

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