(4S,5S)-2,2-Dimethyl-4,5-bis­(3-methyl-2-thioxo-2,3-dihydro-1H-imidazol-1-yl­meth­yl)-1,3-dioxolane

In the chiral title compound, C(15)H(22)N(4)O(2)S(2), there are two mol­ecules in the asymmetric unit with distinctly different conformations, as quanti­fied by torsion angles. The dihedral angles between the thio­imidazole rings are 81.59 (5) and 67.04 (4)°. One mol­ecule exhibits local twofold rot...

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Detalles Bibliográficos
Autores principales: Marshall, Colin, Harrison, William T. A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915016/
https://www.ncbi.nlm.nih.gov/pubmed/21200934
http://dx.doi.org/10.1107/S1600536807055948
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author Marshall, Colin
Harrison, William T. A.
author_facet Marshall, Colin
Harrison, William T. A.
author_sort Marshall, Colin
collection PubMed
description In the chiral title compound, C(15)H(22)N(4)O(2)S(2), there are two mol­ecules in the asymmetric unit with distinctly different conformations, as quanti­fied by torsion angles. The dihedral angles between the thio­imidazole rings are 81.59 (5) and 67.04 (4)°. One mol­ecule exhibits local twofold rotation symmetry, while the other displays no local symmetry. Inter­molecular C—H⋯O and C—H⋯S inter­actions are observed.
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spelling pubmed-29150162010-12-30 (4S,5S)-2,2-Dimethyl-4,5-bis­(3-methyl-2-thioxo-2,3-dihydro-1H-imidazol-1-yl­meth­yl)-1,3-dioxolane Marshall, Colin Harrison, William T. A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the chiral title compound, C(15)H(22)N(4)O(2)S(2), there are two mol­ecules in the asymmetric unit with distinctly different conformations, as quanti­fied by torsion angles. The dihedral angles between the thio­imidazole rings are 81.59 (5) and 67.04 (4)°. One mol­ecule exhibits local twofold rotation symmetry, while the other displays no local symmetry. Inter­molecular C—H⋯O and C—H⋯S inter­actions are observed. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915016/ /pubmed/21200934 http://dx.doi.org/10.1107/S1600536807055948 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Marshall, Colin
Harrison, William T. A.
(4S,5S)-2,2-Dimethyl-4,5-bis­(3-methyl-2-thioxo-2,3-dihydro-1H-imidazol-1-yl­meth­yl)-1,3-dioxolane
title (4S,5S)-2,2-Dimethyl-4,5-bis­(3-methyl-2-thioxo-2,3-dihydro-1H-imidazol-1-yl­meth­yl)-1,3-dioxolane
title_full (4S,5S)-2,2-Dimethyl-4,5-bis­(3-methyl-2-thioxo-2,3-dihydro-1H-imidazol-1-yl­meth­yl)-1,3-dioxolane
title_fullStr (4S,5S)-2,2-Dimethyl-4,5-bis­(3-methyl-2-thioxo-2,3-dihydro-1H-imidazol-1-yl­meth­yl)-1,3-dioxolane
title_full_unstemmed (4S,5S)-2,2-Dimethyl-4,5-bis­(3-methyl-2-thioxo-2,3-dihydro-1H-imidazol-1-yl­meth­yl)-1,3-dioxolane
title_short (4S,5S)-2,2-Dimethyl-4,5-bis­(3-methyl-2-thioxo-2,3-dihydro-1H-imidazol-1-yl­meth­yl)-1,3-dioxolane
title_sort (4s,5s)-2,2-dimethyl-4,5-bis­(3-methyl-2-thioxo-2,3-dihydro-1h-imidazol-1-yl­meth­yl)-1,3-dioxolane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915016/
https://www.ncbi.nlm.nih.gov/pubmed/21200934
http://dx.doi.org/10.1107/S1600536807055948
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AT harrisonwilliamta 4s5s22dimethyl45bis3methyl2thioxo23dihydro1himidazol1ylmethyl13dioxolane

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