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Bis(tetramethylamonium) bis(2,4,5-carboxybenzoate)–benzene-1,2,4,5-tetracarboxylic acid (1/1)
The asymmetric unit of the title compound, 2C(4)H(12)N(+)·2C(10)H(5)O(8) (−)·C(10)H(6)O(8), consists of a tetramethylamonium cation, an anion derived from the singly deprotonated pyromellitic acid anion, 2,4,5-carboxybenzoate (H(3)bta(−)), and one-half of a benzene-1,2,4,5-tetracarboxylic acid (...
Autores principales: | , , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915027/ https://www.ncbi.nlm.nih.gov/pubmed/21200946 http://dx.doi.org/10.1107/S1600536807062381 |
Sumario: | The asymmetric unit of the title compound, 2C(4)H(12)N(+)·2C(10)H(5)O(8) (−)·C(10)H(6)O(8), consists of a tetramethylamonium cation, an anion derived from the singly deprotonated pyromellitic acid anion, 2,4,5-carboxybenzoate (H(3)bta(−)), and one-half of a benzene-1,2,4,5-tetracarboxylic acid (H(4)bta) molecule, which has the centroid of the aromatic ring positioned at a crystallographic centre of inversion. The H(4)bta and H(3)bta(−) residues are involved in an extensive intermolecular O—H⋯O hydrogen-bonding network, which leads to a three-dimensional supramolecular structure containing one-dimensional channels running parallel to the [001] crystallographic direction. These channels house the tetramethylamonium cations. |
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