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Bis(tetra­methyl­amonium) bis­(2,4,5-carboxy­benzoate)–benzene-1,2,4,5-tetra­carboxylic acid (1/1)

The asymmetric unit of the title compound, 2C(4)H(12)N(+)·2C(10)H(5)O(8) (−)·C(10)H(6)O(8), consists of a tetra­methyl­amonium cation, an anion derived from the singly deprotonated pyromellitic acid anion, 2,4,5-carboxy­benzoate (H(3)bta(−)), and one-half of a benzene-1,2,4,5-tetra­carboxylic acid (...

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Autores principales: Cunha-Silva, Luís, Girginova, Penka I., Trindade, Tito, Rocha, João, Klinowski, Jacek, Almeida Paz, Filipe A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915027/
https://www.ncbi.nlm.nih.gov/pubmed/21200946
http://dx.doi.org/10.1107/S1600536807062381
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author Cunha-Silva, Luís
Girginova, Penka I.
Trindade, Tito
Rocha, João
Klinowski, Jacek
Almeida Paz, Filipe A.
author_facet Cunha-Silva, Luís
Girginova, Penka I.
Trindade, Tito
Rocha, João
Klinowski, Jacek
Almeida Paz, Filipe A.
author_sort Cunha-Silva, Luís
collection PubMed
description The asymmetric unit of the title compound, 2C(4)H(12)N(+)·2C(10)H(5)O(8) (−)·C(10)H(6)O(8), consists of a tetra­methyl­amonium cation, an anion derived from the singly deprotonated pyromellitic acid anion, 2,4,5-carboxy­benzoate (H(3)bta(−)), and one-half of a benzene-1,2,4,5-tetra­carboxylic acid (H(4)bta) mol­ecule, which has the centroid of the aromatic ring positioned at a crystallographic centre of inversion. The H(4)bta and H(3)bta(−) residues are involved in an extensive inter­molecular O—H⋯O hydrogen-bonding network, which leads to a three-dimensional supra­molecular structure containing one-dimensional channels running parallel to the [001] crystallographic direction. These channels house the tetra­methyl­amonium cations.
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spelling pubmed-29150272010-12-30 Bis(tetra­methyl­amonium) bis­(2,4,5-carboxy­benzoate)–benzene-1,2,4,5-tetra­carboxylic acid (1/1) Cunha-Silva, Luís Girginova, Penka I. Trindade, Tito Rocha, João Klinowski, Jacek Almeida Paz, Filipe A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, 2C(4)H(12)N(+)·2C(10)H(5)O(8) (−)·C(10)H(6)O(8), consists of a tetra­methyl­amonium cation, an anion derived from the singly deprotonated pyromellitic acid anion, 2,4,5-carboxy­benzoate (H(3)bta(−)), and one-half of a benzene-1,2,4,5-tetra­carboxylic acid (H(4)bta) mol­ecule, which has the centroid of the aromatic ring positioned at a crystallographic centre of inversion. The H(4)bta and H(3)bta(−) residues are involved in an extensive inter­molecular O—H⋯O hydrogen-bonding network, which leads to a three-dimensional supra­molecular structure containing one-dimensional channels running parallel to the [001] crystallographic direction. These channels house the tetra­methyl­amonium cations. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915027/ /pubmed/21200946 http://dx.doi.org/10.1107/S1600536807062381 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Cunha-Silva, Luís
Girginova, Penka I.
Trindade, Tito
Rocha, João
Klinowski, Jacek
Almeida Paz, Filipe A.
Bis(tetra­methyl­amonium) bis­(2,4,5-carboxy­benzoate)–benzene-1,2,4,5-tetra­carboxylic acid (1/1)
title Bis(tetra­methyl­amonium) bis­(2,4,5-carboxy­benzoate)–benzene-1,2,4,5-tetra­carboxylic acid (1/1)
title_full Bis(tetra­methyl­amonium) bis­(2,4,5-carboxy­benzoate)–benzene-1,2,4,5-tetra­carboxylic acid (1/1)
title_fullStr Bis(tetra­methyl­amonium) bis­(2,4,5-carboxy­benzoate)–benzene-1,2,4,5-tetra­carboxylic acid (1/1)
title_full_unstemmed Bis(tetra­methyl­amonium) bis­(2,4,5-carboxy­benzoate)–benzene-1,2,4,5-tetra­carboxylic acid (1/1)
title_short Bis(tetra­methyl­amonium) bis­(2,4,5-carboxy­benzoate)–benzene-1,2,4,5-tetra­carboxylic acid (1/1)
title_sort bis(tetra­methyl­amonium) bis­(2,4,5-carboxy­benzoate)–benzene-1,2,4,5-tetra­carboxylic acid (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915027/
https://www.ncbi.nlm.nih.gov/pubmed/21200946
http://dx.doi.org/10.1107/S1600536807062381
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