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Bis(tetramethylamonium) bis(2,4,5-carboxybenzoate)–benzene-1,2,4,5-tetracarboxylic acid (1/1)
The asymmetric unit of the title compound, 2C(4)H(12)N(+)·2C(10)H(5)O(8) (−)·C(10)H(6)O(8), consists of a tetramethylamonium cation, an anion derived from the singly deprotonated pyromellitic acid anion, 2,4,5-carboxybenzoate (H(3)bta(−)), and one-half of a benzene-1,2,4,5-tetracarboxylic acid (...
Autores principales: | , , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915027/ https://www.ncbi.nlm.nih.gov/pubmed/21200946 http://dx.doi.org/10.1107/S1600536807062381 |
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author | Cunha-Silva, Luís Girginova, Penka I. Trindade, Tito Rocha, João Klinowski, Jacek Almeida Paz, Filipe A. |
author_facet | Cunha-Silva, Luís Girginova, Penka I. Trindade, Tito Rocha, João Klinowski, Jacek Almeida Paz, Filipe A. |
author_sort | Cunha-Silva, Luís |
collection | PubMed |
description | The asymmetric unit of the title compound, 2C(4)H(12)N(+)·2C(10)H(5)O(8) (−)·C(10)H(6)O(8), consists of a tetramethylamonium cation, an anion derived from the singly deprotonated pyromellitic acid anion, 2,4,5-carboxybenzoate (H(3)bta(−)), and one-half of a benzene-1,2,4,5-tetracarboxylic acid (H(4)bta) molecule, which has the centroid of the aromatic ring positioned at a crystallographic centre of inversion. The H(4)bta and H(3)bta(−) residues are involved in an extensive intermolecular O—H⋯O hydrogen-bonding network, which leads to a three-dimensional supramolecular structure containing one-dimensional channels running parallel to the [001] crystallographic direction. These channels house the tetramethylamonium cations. |
format | Text |
id | pubmed-2915027 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29150272010-12-30 Bis(tetramethylamonium) bis(2,4,5-carboxybenzoate)–benzene-1,2,4,5-tetracarboxylic acid (1/1) Cunha-Silva, Luís Girginova, Penka I. Trindade, Tito Rocha, João Klinowski, Jacek Almeida Paz, Filipe A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, 2C(4)H(12)N(+)·2C(10)H(5)O(8) (−)·C(10)H(6)O(8), consists of a tetramethylamonium cation, an anion derived from the singly deprotonated pyromellitic acid anion, 2,4,5-carboxybenzoate (H(3)bta(−)), and one-half of a benzene-1,2,4,5-tetracarboxylic acid (H(4)bta) molecule, which has the centroid of the aromatic ring positioned at a crystallographic centre of inversion. The H(4)bta and H(3)bta(−) residues are involved in an extensive intermolecular O—H⋯O hydrogen-bonding network, which leads to a three-dimensional supramolecular structure containing one-dimensional channels running parallel to the [001] crystallographic direction. These channels house the tetramethylamonium cations. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915027/ /pubmed/21200946 http://dx.doi.org/10.1107/S1600536807062381 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Organic Papers Cunha-Silva, Luís Girginova, Penka I. Trindade, Tito Rocha, João Klinowski, Jacek Almeida Paz, Filipe A. Bis(tetramethylamonium) bis(2,4,5-carboxybenzoate)–benzene-1,2,4,5-tetracarboxylic acid (1/1) |
title | Bis(tetramethylamonium) bis(2,4,5-carboxybenzoate)–benzene-1,2,4,5-tetracarboxylic acid (1/1) |
title_full | Bis(tetramethylamonium) bis(2,4,5-carboxybenzoate)–benzene-1,2,4,5-tetracarboxylic acid (1/1) |
title_fullStr | Bis(tetramethylamonium) bis(2,4,5-carboxybenzoate)–benzene-1,2,4,5-tetracarboxylic acid (1/1) |
title_full_unstemmed | Bis(tetramethylamonium) bis(2,4,5-carboxybenzoate)–benzene-1,2,4,5-tetracarboxylic acid (1/1) |
title_short | Bis(tetramethylamonium) bis(2,4,5-carboxybenzoate)–benzene-1,2,4,5-tetracarboxylic acid (1/1) |
title_sort | bis(tetramethylamonium) bis(2,4,5-carboxybenzoate)–benzene-1,2,4,5-tetracarboxylic acid (1/1) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915027/ https://www.ncbi.nlm.nih.gov/pubmed/21200946 http://dx.doi.org/10.1107/S1600536807062381 |
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