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2′-(3-Hydroxybenzylidene)pyrazine-2-carbohydrazide monohydrate
The title compound, C(12)H(10)N(4)O(2)·H(2)O, was synthesized by the reaction of pyrazine-2-carboxylic acid hydrazide and 3-hydroxybenzaldehyde in ethanol. In the crystal structure, the organic molecules are linked into extended chains by intermolecular N(amide)—H⋯O(hydroxy) hydrogen bonds. Addi...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915038/ https://www.ncbi.nlm.nih.gov/pubmed/21200959 http://dx.doi.org/10.1107/S1600536807062708 |
Sumario: | The title compound, C(12)H(10)N(4)O(2)·H(2)O, was synthesized by the reaction of pyrazine-2-carboxylic acid hydrazide and 3-hydroxybenzaldehyde in ethanol. In the crystal structure, the organic molecules are linked into extended chains by intermolecular N(amide)—H⋯O(hydroxy) hydrogen bonds. Additional hydrogen bonds between the water molecule and three adjacent organic molecules, as well as face-to-face π–π stacking interactions between the benzene and pyrazine rings [centroid-to-centroid separation = 3.669 (2) Å and offset = 1.362 Å], link the molecules into a three-dimensional framework. |
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