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2-Chloro-N-(2,4-dimethylphenyl)acetamide
The conformation of the N—H bond in the structure of the title compound, C(10)H(12)ClNO, is syn to the ortho methyl group, similar to that observed with respect to the meta methyl group in 2-chloro-N-(3-methylphenyl)acetamide and the ortho-chloro group in 2-chloro-N-(2-chlorophenyl)acetamide. Th...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2007
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915041/ https://www.ncbi.nlm.nih.gov/pubmed/21200962 http://dx.doi.org/10.1107/S1600536807062563 |
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author | Gowda, B. Thimme Foro, Sabine Fuess, Hartmut |
author_facet | Gowda, B. Thimme Foro, Sabine Fuess, Hartmut |
author_sort | Gowda, B. Thimme |
collection | PubMed |
description | The conformation of the N—H bond in the structure of the title compound, C(10)H(12)ClNO, is syn to the ortho methyl group, similar to that observed with respect to the meta methyl group in 2-chloro-N-(3-methylphenyl)acetamide and the ortho-chloro group in 2-chloro-N-(2-chlorophenyl)acetamide. The geometric parameters are similar to those of other acetanilides. The molecules are linked into chains through intermolecular N—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2915041 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29150412010-12-30 2-Chloro-N-(2,4-dimethylphenyl)acetamide Gowda, B. Thimme Foro, Sabine Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers The conformation of the N—H bond in the structure of the title compound, C(10)H(12)ClNO, is syn to the ortho methyl group, similar to that observed with respect to the meta methyl group in 2-chloro-N-(3-methylphenyl)acetamide and the ortho-chloro group in 2-chloro-N-(2-chlorophenyl)acetamide. The geometric parameters are similar to those of other acetanilides. The molecules are linked into chains through intermolecular N—H⋯O hydrogen bonds. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915041/ /pubmed/21200962 http://dx.doi.org/10.1107/S1600536807062563 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Organic Papers Gowda, B. Thimme Foro, Sabine Fuess, Hartmut 2-Chloro-N-(2,4-dimethylphenyl)acetamide |
title | 2-Chloro-N-(2,4-dimethylphenyl)acetamide |
title_full | 2-Chloro-N-(2,4-dimethylphenyl)acetamide |
title_fullStr | 2-Chloro-N-(2,4-dimethylphenyl)acetamide |
title_full_unstemmed | 2-Chloro-N-(2,4-dimethylphenyl)acetamide |
title_short | 2-Chloro-N-(2,4-dimethylphenyl)acetamide |
title_sort | 2-chloro-n-(2,4-dimethylphenyl)acetamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915041/ https://www.ncbi.nlm.nih.gov/pubmed/21200962 http://dx.doi.org/10.1107/S1600536807062563 |
work_keys_str_mv | AT gowdabthimme 2chloron24dimethylphenylacetamide AT forosabine 2chloron24dimethylphenylacetamide AT fuesshartmut 2chloron24dimethylphenylacetamide |