1′-Methyl-4′-(1-naphth­yl)-3′′-(1-naphthyl­methyl­ene)acenaphthene-1-spiro-2′-pyrrolidine-3′-spiro-1′′-cyclo­hexane-2,2′′-dione

In the title compound, C(42)H(33)NO(2), the six-membered cyclo­hexa­none ring adopts a slightly distorted chair conformation and the five-membered pyrrolidine ring is in an envelope conformation. The mol­ecular structure features four intra­molecular C—H⋯O inter­actions and an intra­molecular C—H⋯π...

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Detalles Bibliográficos
Autores principales: Athimoolam, S., Radha, V. Anu, Bahadur, S. Asath, Kumar, R. Ranjith, Perumal, S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915050/
https://www.ncbi.nlm.nih.gov/pubmed/21200972
http://dx.doi.org/10.1107/S1600536807061387
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author Athimoolam, S.
Radha, V. Anu
Bahadur, S. Asath
Kumar, R. Ranjith
Perumal, S.
author_facet Athimoolam, S.
Radha, V. Anu
Bahadur, S. Asath
Kumar, R. Ranjith
Perumal, S.
author_sort Athimoolam, S.
collection PubMed
description In the title compound, C(42)H(33)NO(2), the six-membered cyclo­hexa­none ring adopts a slightly distorted chair conformation and the five-membered pyrrolidine ring is in an envelope conformation. The mol­ecular structure features four intra­molecular C—H⋯O inter­actions and an intra­molecular C—H⋯π inter­action. Furthermore, the crystal packing is stabilized by an inter­molecular C—H⋯O and three inter­molecular C—H⋯π inter­actions.
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spelling pubmed-29150502010-12-30 1′-Methyl-4′-(1-naphth­yl)-3′′-(1-naphthyl­methyl­ene)acenaphthene-1-spiro-2′-pyrrolidine-3′-spiro-1′′-cyclo­hexane-2,2′′-dione Athimoolam, S. Radha, V. Anu Bahadur, S. Asath Kumar, R. Ranjith Perumal, S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(42)H(33)NO(2), the six-membered cyclo­hexa­none ring adopts a slightly distorted chair conformation and the five-membered pyrrolidine ring is in an envelope conformation. The mol­ecular structure features four intra­molecular C—H⋯O inter­actions and an intra­molecular C—H⋯π inter­action. Furthermore, the crystal packing is stabilized by an inter­molecular C—H⋯O and three inter­molecular C—H⋯π inter­actions. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915050/ /pubmed/21200972 http://dx.doi.org/10.1107/S1600536807061387 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Athimoolam, S.
Radha, V. Anu
Bahadur, S. Asath
Kumar, R. Ranjith
Perumal, S.
1′-Methyl-4′-(1-naphth­yl)-3′′-(1-naphthyl­methyl­ene)acenaphthene-1-spiro-2′-pyrrolidine-3′-spiro-1′′-cyclo­hexane-2,2′′-dione
title 1′-Methyl-4′-(1-naphth­yl)-3′′-(1-naphthyl­methyl­ene)acenaphthene-1-spiro-2′-pyrrolidine-3′-spiro-1′′-cyclo­hexane-2,2′′-dione
title_full 1′-Methyl-4′-(1-naphth­yl)-3′′-(1-naphthyl­methyl­ene)acenaphthene-1-spiro-2′-pyrrolidine-3′-spiro-1′′-cyclo­hexane-2,2′′-dione
title_fullStr 1′-Methyl-4′-(1-naphth­yl)-3′′-(1-naphthyl­methyl­ene)acenaphthene-1-spiro-2′-pyrrolidine-3′-spiro-1′′-cyclo­hexane-2,2′′-dione
title_full_unstemmed 1′-Methyl-4′-(1-naphth­yl)-3′′-(1-naphthyl­methyl­ene)acenaphthene-1-spiro-2′-pyrrolidine-3′-spiro-1′′-cyclo­hexane-2,2′′-dione
title_short 1′-Methyl-4′-(1-naphth­yl)-3′′-(1-naphthyl­methyl­ene)acenaphthene-1-spiro-2′-pyrrolidine-3′-spiro-1′′-cyclo­hexane-2,2′′-dione
title_sort 1′-methyl-4′-(1-naphth­yl)-3′′-(1-naphthyl­methyl­ene)acenaphthene-1-spiro-2′-pyrrolidine-3′-spiro-1′′-cyclo­hexane-2,2′′-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915050/
https://www.ncbi.nlm.nih.gov/pubmed/21200972
http://dx.doi.org/10.1107/S1600536807061387
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AT perumals 1methyl41naphthyl31naphthylmethyleneacenaphthene1spiro2pyrrolidine3spiro1cyclohexane22dione

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