[2,6-Dioxo-1,2,3,6-tetra­hydro­pyrim­idine-4-carboxyl­ato(2−)]bis(pyrazino[2,3-f][1,10]phenanthroline)cobalt(II) dihydrate

The title complex, [Co(C(5)H(2)N(2)O(4))(C(14)H(8)N(4))(2)]·2H(2)O, features a slightly distorted octa­hedral geometry for Co due to the sterical requirements of the orotic acid and pyrazino[2,3-f][1,10]phenanthroline ligands. Inter­molecular hydrogen bonding between the uncoordinated water mol­ecul...

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Detalles Bibliográficos
Autores principales: Wu, Rentao, Li, Jikun, Zheng, Zebao, Duan, Wenzeng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915054/
https://www.ncbi.nlm.nih.gov/pubmed/21200459
http://dx.doi.org/10.1107/S1600536807064495
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author Wu, Rentao
Li, Jikun
Zheng, Zebao
Duan, Wenzeng
author_facet Wu, Rentao
Li, Jikun
Zheng, Zebao
Duan, Wenzeng
author_sort Wu, Rentao
collection PubMed
description The title complex, [Co(C(5)H(2)N(2)O(4))(C(14)H(8)N(4))(2)]·2H(2)O, features a slightly distorted octa­hedral geometry for Co due to the sterical requirements of the orotic acid and pyrazino[2,3-f][1,10]phenanthroline ligands. Inter­molecular hydrogen bonding between the uncoordinated water mol­ecules and the ligand stablizes the structure of the complex.
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spelling pubmed-29150542010-12-30 [2,6-Dioxo-1,2,3,6-tetra­hydro­pyrim­idine-4-carboxyl­ato(2−)]bis(pyrazino[2,3-f][1,10]phenanthroline)cobalt(II) dihydrate Wu, Rentao Li, Jikun Zheng, Zebao Duan, Wenzeng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Co(C(5)H(2)N(2)O(4))(C(14)H(8)N(4))(2)]·2H(2)O, features a slightly distorted octa­hedral geometry for Co due to the sterical requirements of the orotic acid and pyrazino[2,3-f][1,10]phenanthroline ligands. Inter­molecular hydrogen bonding between the uncoordinated water mol­ecules and the ligand stablizes the structure of the complex. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915054/ /pubmed/21200459 http://dx.doi.org/10.1107/S1600536807064495 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Wu, Rentao
Li, Jikun
Zheng, Zebao
Duan, Wenzeng
[2,6-Dioxo-1,2,3,6-tetra­hydro­pyrim­idine-4-carboxyl­ato(2−)]bis(pyrazino[2,3-f][1,10]phenanthroline)cobalt(II) dihydrate
title [2,6-Dioxo-1,2,3,6-tetra­hydro­pyrim­idine-4-carboxyl­ato(2−)]bis(pyrazino[2,3-f][1,10]phenanthroline)cobalt(II) dihydrate
title_full [2,6-Dioxo-1,2,3,6-tetra­hydro­pyrim­idine-4-carboxyl­ato(2−)]bis(pyrazino[2,3-f][1,10]phenanthroline)cobalt(II) dihydrate
title_fullStr [2,6-Dioxo-1,2,3,6-tetra­hydro­pyrim­idine-4-carboxyl­ato(2−)]bis(pyrazino[2,3-f][1,10]phenanthroline)cobalt(II) dihydrate
title_full_unstemmed [2,6-Dioxo-1,2,3,6-tetra­hydro­pyrim­idine-4-carboxyl­ato(2−)]bis(pyrazino[2,3-f][1,10]phenanthroline)cobalt(II) dihydrate
title_short [2,6-Dioxo-1,2,3,6-tetra­hydro­pyrim­idine-4-carboxyl­ato(2−)]bis(pyrazino[2,3-f][1,10]phenanthroline)cobalt(II) dihydrate
title_sort [2,6-dioxo-1,2,3,6-tetra­hydro­pyrim­idine-4-carboxyl­ato(2−)]bis(pyrazino[2,3-f][1,10]phenanthroline)cobalt(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915054/
https://www.ncbi.nlm.nih.gov/pubmed/21200459
http://dx.doi.org/10.1107/S1600536807064495
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AT zhengzebao 26dioxo1236tetrahydropyrimidine4carboxylato2bispyrazino23f110phenanthrolinecobaltiidihydrate
AT duanwenzeng 26dioxo1236tetrahydropyrimidine4carboxylato2bispyrazino23f110phenanthrolinecobaltiidihydrate

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