Diaqua­bis(2-carboxy­benzoato-κO)nickel(II)

In the title compound, [Ni(C(8)H(5)O(4))(2)(H(2)O)(2)], the Ni(II) atom lies on an inversion centre and exhibits a square-planar geometry incorporating two phthalate and two water O atoms. The nickel complex is stabilized by intra­molecular inter­actions involving water O atoms and H atoms of the ph...

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Detalles Bibliográficos
Autores principales: Xuan, Ya-Wen, Wu, Wen, Xie, Dong-Po, Yuan, Nai-Xiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915055/
https://www.ncbi.nlm.nih.gov/pubmed/21200460
http://dx.doi.org/10.1107/S1600536807064604
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author Xuan, Ya-Wen
Wu, Wen
Xie, Dong-Po
Yuan, Nai-Xiang
author_facet Xuan, Ya-Wen
Wu, Wen
Xie, Dong-Po
Yuan, Nai-Xiang
author_sort Xuan, Ya-Wen
collection PubMed
description In the title compound, [Ni(C(8)H(5)O(4))(2)(H(2)O)(2)], the Ni(II) atom lies on an inversion centre and exhibits a square-planar geometry incorporating two phthalate and two water O atoms. The nickel complex is stabilized by intra­molecular inter­actions involving water O atoms and H atoms of the phthalate groups. It forms one-dimensional zigzag chains along the b axis which are held together via π–π stacking inter­actions (3.647 Å) between the benzene rings of the phthalate groups. The adjacent chains are also hydrogen bonded, resulting in a three-dimensional supra­molecular network.
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spelling pubmed-29150552010-12-30 Diaqua­bis(2-carboxy­benzoato-κO)nickel(II) Xuan, Ya-Wen Wu, Wen Xie, Dong-Po Yuan, Nai-Xiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(8)H(5)O(4))(2)(H(2)O)(2)], the Ni(II) atom lies on an inversion centre and exhibits a square-planar geometry incorporating two phthalate and two water O atoms. The nickel complex is stabilized by intra­molecular inter­actions involving water O atoms and H atoms of the phthalate groups. It forms one-dimensional zigzag chains along the b axis which are held together via π–π stacking inter­actions (3.647 Å) between the benzene rings of the phthalate groups. The adjacent chains are also hydrogen bonded, resulting in a three-dimensional supra­molecular network. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915055/ /pubmed/21200460 http://dx.doi.org/10.1107/S1600536807064604 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Xuan, Ya-Wen
Wu, Wen
Xie, Dong-Po
Yuan, Nai-Xiang
Diaqua­bis(2-carboxy­benzoato-κO)nickel(II)
title Diaqua­bis(2-carboxy­benzoato-κO)nickel(II)
title_full Diaqua­bis(2-carboxy­benzoato-κO)nickel(II)
title_fullStr Diaqua­bis(2-carboxy­benzoato-κO)nickel(II)
title_full_unstemmed Diaqua­bis(2-carboxy­benzoato-κO)nickel(II)
title_short Diaqua­bis(2-carboxy­benzoato-κO)nickel(II)
title_sort diaqua­bis(2-carboxy­benzoato-κo)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915055/
https://www.ncbi.nlm.nih.gov/pubmed/21200460
http://dx.doi.org/10.1107/S1600536807064604
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AT wuwen diaquabis2carboxybenzoatokonickelii
AT xiedongpo diaquabis2carboxybenzoatokonickelii
AT yuannaixiang diaquabis2carboxybenzoatokonickelii

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