Cargando…

Tetra­kis(μ-propanoato-κ(2) O:O′)bis­[(1,10-phenanthroline-κ(2) N,N′)(propanoato-κ(2) O,O′)samarium(III)]

The title complex, [Sm(2)(C(3)H(5)O(2))(6)(C(12)H(8)N(2))(2)], is a dinuclear centrosymmetric mol­ecule, in which two crystallographically equivalent Sm atoms, separated by 3.9502 (2) Å, are bridged by four propanoate anions. Each Sm atom is coordinated by two N atoms from one chelating phenanthroli...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Chun-Xiang, Li, Zhi-Feng, Xiong, Shu-Hua, Wang, Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915056/
https://www.ncbi.nlm.nih.gov/pubmed/21200461
http://dx.doi.org/10.1107/S1600536807064720
_version_ 1782184849415602176
author Wang, Chun-Xiang
Li, Zhi-Feng
Xiong, Shu-Hua
Wang, Ping
author_facet Wang, Chun-Xiang
Li, Zhi-Feng
Xiong, Shu-Hua
Wang, Ping
author_sort Wang, Chun-Xiang
collection PubMed
description The title complex, [Sm(2)(C(3)H(5)O(2))(6)(C(12)H(8)N(2))(2)], is a dinuclear centrosymmetric mol­ecule, in which two crystallographically equivalent Sm atoms, separated by 3.9502 (2) Å, are bridged by four propanoate anions. Each Sm atom is coordinated by two N atoms from one chelating phenanthroline ligand and seven carboxylate O atoms from five propanoate anions, to form a distorted tricapped trigonal prism.
format Text
id pubmed-2915056
institution National Center for Biotechnology Information
language English
publishDate 2007
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29150562010-12-30 Tetra­kis(μ-propanoato-κ(2) O:O′)bis­[(1,10-phenanthroline-κ(2) N,N′)(propanoato-κ(2) O,O′)samarium(III)] Wang, Chun-Xiang Li, Zhi-Feng Xiong, Shu-Hua Wang, Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Sm(2)(C(3)H(5)O(2))(6)(C(12)H(8)N(2))(2)], is a dinuclear centrosymmetric mol­ecule, in which two crystallographically equivalent Sm atoms, separated by 3.9502 (2) Å, are bridged by four propanoate anions. Each Sm atom is coordinated by two N atoms from one chelating phenanthroline ligand and seven carboxylate O atoms from five propanoate anions, to form a distorted tricapped trigonal prism. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915056/ /pubmed/21200461 http://dx.doi.org/10.1107/S1600536807064720 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Wang, Chun-Xiang
Li, Zhi-Feng
Xiong, Shu-Hua
Wang, Ping
Tetra­kis(μ-propanoato-κ(2) O:O′)bis­[(1,10-phenanthroline-κ(2) N,N′)(propanoato-κ(2) O,O′)samarium(III)]
title Tetra­kis(μ-propanoato-κ(2) O:O′)bis­[(1,10-phenanthroline-κ(2) N,N′)(propanoato-κ(2) O,O′)samarium(III)]
title_full Tetra­kis(μ-propanoato-κ(2) O:O′)bis­[(1,10-phenanthroline-κ(2) N,N′)(propanoato-κ(2) O,O′)samarium(III)]
title_fullStr Tetra­kis(μ-propanoato-κ(2) O:O′)bis­[(1,10-phenanthroline-κ(2) N,N′)(propanoato-κ(2) O,O′)samarium(III)]
title_full_unstemmed Tetra­kis(μ-propanoato-κ(2) O:O′)bis­[(1,10-phenanthroline-κ(2) N,N′)(propanoato-κ(2) O,O′)samarium(III)]
title_short Tetra­kis(μ-propanoato-κ(2) O:O′)bis­[(1,10-phenanthroline-κ(2) N,N′)(propanoato-κ(2) O,O′)samarium(III)]
title_sort tetra­kis(μ-propanoato-κ(2) o:o′)bis­[(1,10-phenanthroline-κ(2) n,n′)(propanoato-κ(2) o,o′)samarium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915056/
https://www.ncbi.nlm.nih.gov/pubmed/21200461
http://dx.doi.org/10.1107/S1600536807064720
work_keys_str_mv AT wangchunxiang tetrakismpropanoatok2oobis110phenanthrolinek2nnpropanoatok2oosamariumiii
AT lizhifeng tetrakismpropanoatok2oobis110phenanthrolinek2nnpropanoatok2oosamariumiii
AT xiongshuhua tetrakismpropanoatok2oobis110phenanthrolinek2nnpropanoatok2oosamariumiii
AT wangping tetrakismpropanoatok2oobis110phenanthrolinek2nnpropanoatok2oosamariumiii