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Tetrakis(μ-propanoato-κ(2) O:O′)bis[(1,10-phenanthroline-κ(2) N,N′)(propanoato-κ(2) O,O′)samarium(III)]
The title complex, [Sm(2)(C(3)H(5)O(2))(6)(C(12)H(8)N(2))(2)], is a dinuclear centrosymmetric molecule, in which two crystallographically equivalent Sm atoms, separated by 3.9502 (2) Å, are bridged by four propanoate anions. Each Sm atom is coordinated by two N atoms from one chelating phenanthroli...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915056/ https://www.ncbi.nlm.nih.gov/pubmed/21200461 http://dx.doi.org/10.1107/S1600536807064720 |
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author | Wang, Chun-Xiang Li, Zhi-Feng Xiong, Shu-Hua Wang, Ping |
author_facet | Wang, Chun-Xiang Li, Zhi-Feng Xiong, Shu-Hua Wang, Ping |
author_sort | Wang, Chun-Xiang |
collection | PubMed |
description | The title complex, [Sm(2)(C(3)H(5)O(2))(6)(C(12)H(8)N(2))(2)], is a dinuclear centrosymmetric molecule, in which two crystallographically equivalent Sm atoms, separated by 3.9502 (2) Å, are bridged by four propanoate anions. Each Sm atom is coordinated by two N atoms from one chelating phenanthroline ligand and seven carboxylate O atoms from five propanoate anions, to form a distorted tricapped trigonal prism. |
format | Text |
id | pubmed-2915056 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29150562010-12-30 Tetrakis(μ-propanoato-κ(2) O:O′)bis[(1,10-phenanthroline-κ(2) N,N′)(propanoato-κ(2) O,O′)samarium(III)] Wang, Chun-Xiang Li, Zhi-Feng Xiong, Shu-Hua Wang, Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Sm(2)(C(3)H(5)O(2))(6)(C(12)H(8)N(2))(2)], is a dinuclear centrosymmetric molecule, in which two crystallographically equivalent Sm atoms, separated by 3.9502 (2) Å, are bridged by four propanoate anions. Each Sm atom is coordinated by two N atoms from one chelating phenanthroline ligand and seven carboxylate O atoms from five propanoate anions, to form a distorted tricapped trigonal prism. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915056/ /pubmed/21200461 http://dx.doi.org/10.1107/S1600536807064720 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Wang, Chun-Xiang Li, Zhi-Feng Xiong, Shu-Hua Wang, Ping Tetrakis(μ-propanoato-κ(2) O:O′)bis[(1,10-phenanthroline-κ(2) N,N′)(propanoato-κ(2) O,O′)samarium(III)] |
title | Tetrakis(μ-propanoato-κ(2)
O:O′)bis[(1,10-phenanthroline-κ(2)
N,N′)(propanoato-κ(2)
O,O′)samarium(III)] |
title_full | Tetrakis(μ-propanoato-κ(2)
O:O′)bis[(1,10-phenanthroline-κ(2)
N,N′)(propanoato-κ(2)
O,O′)samarium(III)] |
title_fullStr | Tetrakis(μ-propanoato-κ(2)
O:O′)bis[(1,10-phenanthroline-κ(2)
N,N′)(propanoato-κ(2)
O,O′)samarium(III)] |
title_full_unstemmed | Tetrakis(μ-propanoato-κ(2)
O:O′)bis[(1,10-phenanthroline-κ(2)
N,N′)(propanoato-κ(2)
O,O′)samarium(III)] |
title_short | Tetrakis(μ-propanoato-κ(2)
O:O′)bis[(1,10-phenanthroline-κ(2)
N,N′)(propanoato-κ(2)
O,O′)samarium(III)] |
title_sort | tetrakis(μ-propanoato-κ(2)
o:o′)bis[(1,10-phenanthroline-κ(2)
n,n′)(propanoato-κ(2)
o,o′)samarium(iii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915056/ https://www.ncbi.nlm.nih.gov/pubmed/21200461 http://dx.doi.org/10.1107/S1600536807064720 |
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