Poly[[[tetra­aqua­cobalt(II)]-μ-bipyridine] terephthalate]

The Co(II) atom in the title complex, {[Co(C(10)H(8)N(2))(H(2)O)(4)](C(8)H(4)O(4))}(n), is coordinated by two N atoms of two bipyridine ligands and four O atoms of four water mol­ecules in an octahedral geometry. The one-dimensional [Co(C(10)H(8)N(2))(H(2)O)(4)](2+) cation chain is further extended...

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Detalles Bibliográficos
Autor principal: Xu, Haiyun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915057/
https://www.ncbi.nlm.nih.gov/pubmed/21200462
http://dx.doi.org/10.1107/S1600536807064045
Descripción
Sumario:The Co(II) atom in the title complex, {[Co(C(10)H(8)N(2))(H(2)O)(4)](C(8)H(4)O(4))}(n), is coordinated by two N atoms of two bipyridine ligands and four O atoms of four water mol­ecules in an octahedral geometry. The one-dimensional [Co(C(10)H(8)N(2))(H(2)O)(4)](2+) cation chain is further extended into a supra­molecular network via O–H⋯O hydrogen-bond inter­actions. The Co atom lies on a twofold rotation axis; another twofold rotation axis passes through the carboxylate carbon atoms and the attached ring C atoms.

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