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Poly[[[tetraaquacobalt(II)]-μ-bipyridine] terephthalate]
The Co(II) atom in the title complex, {[Co(C(10)H(8)N(2))(H(2)O)(4)](C(8)H(4)O(4))}(n), is coordinated by two N atoms of two bipyridine ligands and four O atoms of four water molecules in an octahedral geometry. The one-dimensional [Co(C(10)H(8)N(2))(H(2)O)(4)](2+) cation chain is further extended...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2007
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915057/ https://www.ncbi.nlm.nih.gov/pubmed/21200462 http://dx.doi.org/10.1107/S1600536807064045 |
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author | Xu, Haiyun |
author_facet | Xu, Haiyun |
author_sort | Xu, Haiyun |
collection | PubMed |
description | The Co(II) atom in the title complex, {[Co(C(10)H(8)N(2))(H(2)O)(4)](C(8)H(4)O(4))}(n), is coordinated by two N atoms of two bipyridine ligands and four O atoms of four water molecules in an octahedral geometry. The one-dimensional [Co(C(10)H(8)N(2))(H(2)O)(4)](2+) cation chain is further extended into a supramolecular network via O–H⋯O hydrogen-bond interactions. The Co atom lies on a twofold rotation axis; another twofold rotation axis passes through the carboxylate carbon atoms and the attached ring C atoms. |
format | Text |
id | pubmed-2915057 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29150572010-12-30 Poly[[[tetraaquacobalt(II)]-μ-bipyridine] terephthalate] Xu, Haiyun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Co(II) atom in the title complex, {[Co(C(10)H(8)N(2))(H(2)O)(4)](C(8)H(4)O(4))}(n), is coordinated by two N atoms of two bipyridine ligands and four O atoms of four water molecules in an octahedral geometry. The one-dimensional [Co(C(10)H(8)N(2))(H(2)O)(4)](2+) cation chain is further extended into a supramolecular network via O–H⋯O hydrogen-bond interactions. The Co atom lies on a twofold rotation axis; another twofold rotation axis passes through the carboxylate carbon atoms and the attached ring C atoms. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915057/ /pubmed/21200462 http://dx.doi.org/10.1107/S1600536807064045 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Xu, Haiyun Poly[[[tetraaquacobalt(II)]-μ-bipyridine] terephthalate] |
title | Poly[[[tetraaquacobalt(II)]-μ-bipyridine] terephthalate] |
title_full | Poly[[[tetraaquacobalt(II)]-μ-bipyridine] terephthalate] |
title_fullStr | Poly[[[tetraaquacobalt(II)]-μ-bipyridine] terephthalate] |
title_full_unstemmed | Poly[[[tetraaquacobalt(II)]-μ-bipyridine] terephthalate] |
title_short | Poly[[[tetraaquacobalt(II)]-μ-bipyridine] terephthalate] |
title_sort | poly[[[tetraaquacobalt(ii)]-μ-bipyridine] terephthalate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915057/ https://www.ncbi.nlm.nih.gov/pubmed/21200462 http://dx.doi.org/10.1107/S1600536807064045 |
work_keys_str_mv | AT xuhaiyun polytetraaquacobaltiimbipyridineterephthalate |