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catena-Poly[[[diaqua­iron(II)]-μ-pyrazine-2,3-dicarboxyl­ato] dihydrate]

The crystal structure of the title compound, {[Fe(C(6)H(2)N(2)O(4))(H(2)O)(2)]·2H(2)O}(n), was synthesized by a diffusion method. It has a one-dimensional polymeric chain structure and the chains are further connected into a three-dimensional structure by hydrogen bonds. The Fe(II) ion has a distort...

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Detalles Bibliográficos
Autores principales: Xu, Haiyun, Ma, Huailing, Xu, Maotian, Zhao, Wenxian, Guo, Baoguo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915058/
https://www.ncbi.nlm.nih.gov/pubmed/21200463
http://dx.doi.org/10.1107/S1600536807064501
Descripción
Sumario:The crystal structure of the title compound, {[Fe(C(6)H(2)N(2)O(4))(H(2)O)(2)]·2H(2)O}(n), was synthesized by a diffusion method. It has a one-dimensional polymeric chain structure and the chains are further connected into a three-dimensional structure by hydrogen bonds. The Fe(II) ion has a distorted octa­hedral coordination environment, with two N and two O atoms from the pyrazine-2,3-dicarboxyl­ate ligands in the equatorial plane and with two water mol­ecules in axial positions. The Fe atom lies on a crystallographic centre of symmetry and a twofold rotation axis passes through the pyrazine ring.