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Di-μ-chlorido-bis[chloridobis(dimethyl sulfoxide)dioxidouranium(VI)]
In the crystal structure of the title compound, [U(2)Cl(4)O(4)(C(2)H(6)OS)(4)], the compound has a centrosymmetric dimeric structure bridged by two chloride anions. Each U(VI) atom is seven-coordinate in a pentagonal-bipyramidal geometry. In the equatorial plane of the uranyl unit there are two O a...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915060/ https://www.ncbi.nlm.nih.gov/pubmed/21200466 http://dx.doi.org/10.1107/S1600536807064264 |
Sumario: | In the crystal structure of the title compound, [U(2)Cl(4)O(4)(C(2)H(6)OS)(4)], the compound has a centrosymmetric dimeric structure bridged by two chloride anions. Each U(VI) atom is seven-coordinate in a pentagonal-bipyramidal geometry. In the equatorial plane of the uranyl unit there are two O atoms from non-adjacent dimethyl sulfoxides and three chloride ions (of which two chlorides are bridging). The compound is of interest as an anhydrous starting material of the uranyl(VI) ion. |
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