Di-μ-chlorido-bis­[chloridobis(dimethyl sulfoxide)dioxidouranium(VI)]

In the crystal structure of the title compound, [U(2)Cl(4)O(4)(C(2)H(6)OS)(4)], the compound has a centrosymmetric dimeric structure bridged by two chloride anions. Each U(VI) atom is seven-coordinate in a penta­gonal-bipyramidal geometry. In the equatorial plane of the uranyl unit there are two O a...

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Detalles Bibliográficos
Autores principales: Takao, Koichiro, Ikeda, Yasuhisa
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915060/
https://www.ncbi.nlm.nih.gov/pubmed/21200466
http://dx.doi.org/10.1107/S1600536807064264
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author Takao, Koichiro
Ikeda, Yasuhisa
author_facet Takao, Koichiro
Ikeda, Yasuhisa
author_sort Takao, Koichiro
collection PubMed
description In the crystal structure of the title compound, [U(2)Cl(4)O(4)(C(2)H(6)OS)(4)], the compound has a centrosymmetric dimeric structure bridged by two chloride anions. Each U(VI) atom is seven-coordinate in a penta­gonal-bipyramidal geometry. In the equatorial plane of the uranyl unit there are two O atoms from non-adjacent dimethyl sulfoxides and three chloride ions (of which two chlorides are bridging). The compound is of inter­est as an anhydrous starting material of the uran­yl(VI) ion.
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spelling pubmed-29150602010-12-30 Di-μ-chlorido-bis­[chloridobis(dimethyl sulfoxide)dioxidouranium(VI)] Takao, Koichiro Ikeda, Yasuhisa Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [U(2)Cl(4)O(4)(C(2)H(6)OS)(4)], the compound has a centrosymmetric dimeric structure bridged by two chloride anions. Each U(VI) atom is seven-coordinate in a penta­gonal-bipyramidal geometry. In the equatorial plane of the uranyl unit there are two O atoms from non-adjacent dimethyl sulfoxides and three chloride ions (of which two chlorides are bridging). The compound is of inter­est as an anhydrous starting material of the uran­yl(VI) ion. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915060/ /pubmed/21200466 http://dx.doi.org/10.1107/S1600536807064264 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Takao, Koichiro
Ikeda, Yasuhisa
Di-μ-chlorido-bis­[chloridobis(dimethyl sulfoxide)dioxidouranium(VI)]
title Di-μ-chlorido-bis­[chloridobis(dimethyl sulfoxide)dioxidouranium(VI)]
title_full Di-μ-chlorido-bis­[chloridobis(dimethyl sulfoxide)dioxidouranium(VI)]
title_fullStr Di-μ-chlorido-bis­[chloridobis(dimethyl sulfoxide)dioxidouranium(VI)]
title_full_unstemmed Di-μ-chlorido-bis­[chloridobis(dimethyl sulfoxide)dioxidouranium(VI)]
title_short Di-μ-chlorido-bis­[chloridobis(dimethyl sulfoxide)dioxidouranium(VI)]
title_sort di-μ-chlorido-bis­[chloridobis(dimethyl sulfoxide)dioxidouranium(vi)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915060/
https://www.ncbi.nlm.nih.gov/pubmed/21200466
http://dx.doi.org/10.1107/S1600536807064264
work_keys_str_mv AT takaokoichiro dimchloridobischloridobisdimethylsulfoxidedioxidouraniumvi
AT ikedayasuhisa dimchloridobischloridobisdimethylsulfoxidedioxidouraniumvi

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