Dichloridotriphenyl­anti­mony(V)–bis­(pyrrolidin-1-ylthio­carbon­yl) disulfide (1/1)

The asymmetric unit of the title compound, [Sb(C(6)H(5))(3)Cl(2)]·C(10)H(16)N(2)S(4), comprises a bis­(pyrrolidinylthio­carbamo­yl) mol­ecule and a dichloro­triphenyl­anti­mony(V) complex. In the Sb complex, the central atom is coordinated by three C atoms of the three phenyl ligands and two Cl atom...

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Detalles Bibliográficos
Autores principales: Quan, Li, Yin, Handong, Zhai, Jun, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915061/
https://www.ncbi.nlm.nih.gov/pubmed/21200467
http://dx.doi.org/10.1107/S1600536807063830
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author Quan, Li
Yin, Handong
Zhai, Jun
Wang, Daqi
author_facet Quan, Li
Yin, Handong
Zhai, Jun
Wang, Daqi
author_sort Quan, Li
collection PubMed
description The asymmetric unit of the title compound, [Sb(C(6)H(5))(3)Cl(2)]·C(10)H(16)N(2)S(4), comprises a bis­(pyrrolidinylthio­carbamo­yl) mol­ecule and a dichloro­triphenyl­anti­mony(V) complex. In the Sb complex, the central atom is coordinated by three C atoms of the three phenyl ligands and two Cl atoms in a slightly distorted trigonal-bipyramidal geometry. The thio­carbamoyl units, connected via the disulfide bond, are approximately perpendicular to each other. The mol­ecules are connected by weak C—H⋯S and C—H⋯Cl hydrogen-bonding inter­actions into two one-dimensional supra­molecular chains.
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spelling pubmed-29150612010-12-30 Dichloridotriphenyl­anti­mony(V)–bis­(pyrrolidin-1-ylthio­carbon­yl) disulfide (1/1) Quan, Li Yin, Handong Zhai, Jun Wang, Daqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Sb(C(6)H(5))(3)Cl(2)]·C(10)H(16)N(2)S(4), comprises a bis­(pyrrolidinylthio­carbamo­yl) mol­ecule and a dichloro­triphenyl­anti­mony(V) complex. In the Sb complex, the central atom is coordinated by three C atoms of the three phenyl ligands and two Cl atoms in a slightly distorted trigonal-bipyramidal geometry. The thio­carbamoyl units, connected via the disulfide bond, are approximately perpendicular to each other. The mol­ecules are connected by weak C—H⋯S and C—H⋯Cl hydrogen-bonding inter­actions into two one-dimensional supra­molecular chains. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915061/ /pubmed/21200467 http://dx.doi.org/10.1107/S1600536807063830 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Quan, Li
Yin, Handong
Zhai, Jun
Wang, Daqi
Dichloridotriphenyl­anti­mony(V)–bis­(pyrrolidin-1-ylthio­carbon­yl) disulfide (1/1)
title Dichloridotriphenyl­anti­mony(V)–bis­(pyrrolidin-1-ylthio­carbon­yl) disulfide (1/1)
title_full Dichloridotriphenyl­anti­mony(V)–bis­(pyrrolidin-1-ylthio­carbon­yl) disulfide (1/1)
title_fullStr Dichloridotriphenyl­anti­mony(V)–bis­(pyrrolidin-1-ylthio­carbon­yl) disulfide (1/1)
title_full_unstemmed Dichloridotriphenyl­anti­mony(V)–bis­(pyrrolidin-1-ylthio­carbon­yl) disulfide (1/1)
title_short Dichloridotriphenyl­anti­mony(V)–bis­(pyrrolidin-1-ylthio­carbon­yl) disulfide (1/1)
title_sort dichloridotriphenyl­anti­mony(v)–bis­(pyrrolidin-1-ylthio­carbon­yl) disulfide (1/1)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915061/
https://www.ncbi.nlm.nih.gov/pubmed/21200467
http://dx.doi.org/10.1107/S1600536807063830
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AT yinhandong dichloridotriphenylantimonyvbispyrrolidin1ylthiocarbonyldisulfide11
AT zhaijun dichloridotriphenylantimonyvbispyrrolidin1ylthiocarbonyldisulfide11
AT wangdaqi dichloridotriphenylantimonyvbispyrrolidin1ylthiocarbonyldisulfide11

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