Cyanidophenyl­tris(trimethyl­phosphine)cobalt(II)

The title mol­ecule, [Co(C(6)H(5))(CN)(C(3)H(9)P)(3)], lies on a crystallographic mirror plane with the Co(II) ion coordinated in a distorted square-pyramidal environment with one of the P atoms in the apical position. In the basal plane, the phenyl substituent is trans to the cyanide group with a C...

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Detalles Bibliográficos
Autores principales: Yu, Fengli, Wang, Qibao, Li, Xiaoyan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915065/
https://www.ncbi.nlm.nih.gov/pubmed/21200472
http://dx.doi.org/10.1107/S1600536807064781
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author Yu, Fengli
Wang, Qibao
Li, Xiaoyan
author_facet Yu, Fengli
Wang, Qibao
Li, Xiaoyan
author_sort Yu, Fengli
collection PubMed
description The title mol­ecule, [Co(C(6)H(5))(CN)(C(3)H(9)P)(3)], lies on a crystallographic mirror plane with the Co(II) ion coordinated in a distorted square-pyramidal environment with one of the P atoms in the apical position. In the basal plane, the phenyl substituent is trans to the cyanide group with a C—Co—C angle which is significantly distorted from linearity.
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spelling pubmed-29150652010-12-30 Cyanidophenyl­tris(trimethyl­phosphine)cobalt(II) Yu, Fengli Wang, Qibao Li, Xiaoyan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title mol­ecule, [Co(C(6)H(5))(CN)(C(3)H(9)P)(3)], lies on a crystallographic mirror plane with the Co(II) ion coordinated in a distorted square-pyramidal environment with one of the P atoms in the apical position. In the basal plane, the phenyl substituent is trans to the cyanide group with a C—Co—C angle which is significantly distorted from linearity. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915065/ /pubmed/21200472 http://dx.doi.org/10.1107/S1600536807064781 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Yu, Fengli
Wang, Qibao
Li, Xiaoyan
Cyanidophenyl­tris(trimethyl­phosphine)cobalt(II)
title Cyanidophenyl­tris(trimethyl­phosphine)cobalt(II)
title_full Cyanidophenyl­tris(trimethyl­phosphine)cobalt(II)
title_fullStr Cyanidophenyl­tris(trimethyl­phosphine)cobalt(II)
title_full_unstemmed Cyanidophenyl­tris(trimethyl­phosphine)cobalt(II)
title_short Cyanidophenyl­tris(trimethyl­phosphine)cobalt(II)
title_sort cyanidophenyl­tris(trimethyl­phosphine)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915065/
https://www.ncbi.nlm.nih.gov/pubmed/21200472
http://dx.doi.org/10.1107/S1600536807064781
work_keys_str_mv AT yufengli cyanidophenyltristrimethylphosphinecobaltii
AT wangqibao cyanidophenyltristrimethylphosphinecobaltii
AT lixiaoyan cyanidophenyltristrimethylphosphinecobaltii

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