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Poly[methano­ltetra­kis[μ(3)-5-(4-methoxy­phen­yl)pyrazole-3-carboxyl­ato(2−)]tri­copper(II)disodium(I)

The asymmetric unit of the polymeric title complex, [Cu(3)Na(2)(C(11)H(8)N(2)O(3))(4)(CH(4)O)](n), consists of two Na(I) atoms, three Cu(II) atoms, four 5-(4-methoxy­phen­yl)pyrazole-3-carboxyl­ate ligands and one methanol mol­ecule. The central Cu(II) atom is coordinated by four N atoms from four p...

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Detalles Bibliográficos
Autores principales: An, Yue, Zhou, Guang-Hua, Mu, Ping-Ping, Zhou, Xiao-Xia, Xing, Yong-Heng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915067/
https://www.ncbi.nlm.nih.gov/pubmed/21200474
http://dx.doi.org/10.1107/S1600536807064008
Descripción
Sumario:The asymmetric unit of the polymeric title complex, [Cu(3)Na(2)(C(11)H(8)N(2)O(3))(4)(CH(4)O)](n), consists of two Na(I) atoms, three Cu(II) atoms, four 5-(4-methoxy­phen­yl)pyrazole-3-carboxyl­ate ligands and one methanol mol­ecule. The central Cu(II) atom is coordinated by four N atoms from four pyrazole-3-carboxyl­ate ligands, forming a distorted tetra­hedral (CuN(4)) geometry, while each of the other two Cu(II) atoms is coordinated by two O atoms and two N atoms from the two ligands, forming a slightly distorted square-planar (CuN(2)O(2)) geometry. Each of the two Na(I) atoms is coordinated by five O atoms, forming a distorted octahedral geometry; four O atoms are from the carboxyl­ate groups of the three ligands and the remaining O atom is from the meth­oxy group of the ligand or from the methanol mol­ecule.