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Poly[methanoltetrakis[μ(3)-5-(4-methoxyphenyl)pyrazole-3-carboxylato(2−)]tricopper(II)disodium(I)
The asymmetric unit of the polymeric title complex, [Cu(3)Na(2)(C(11)H(8)N(2)O(3))(4)(CH(4)O)](n), consists of two Na(I) atoms, three Cu(II) atoms, four 5-(4-methoxyphenyl)pyrazole-3-carboxylate ligands and one methanol molecule. The central Cu(II) atom is coordinated by four N atoms from four p...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915067/ https://www.ncbi.nlm.nih.gov/pubmed/21200474 http://dx.doi.org/10.1107/S1600536807064008 |
Sumario: | The asymmetric unit of the polymeric title complex, [Cu(3)Na(2)(C(11)H(8)N(2)O(3))(4)(CH(4)O)](n), consists of two Na(I) atoms, three Cu(II) atoms, four 5-(4-methoxyphenyl)pyrazole-3-carboxylate ligands and one methanol molecule. The central Cu(II) atom is coordinated by four N atoms from four pyrazole-3-carboxylate ligands, forming a distorted tetrahedral (CuN(4)) geometry, while each of the other two Cu(II) atoms is coordinated by two O atoms and two N atoms from the two ligands, forming a slightly distorted square-planar (CuN(2)O(2)) geometry. Each of the two Na(I) atoms is coordinated by five O atoms, forming a distorted octahedral geometry; four O atoms are from the carboxylate groups of the three ligands and the remaining O atom is from the methoxy group of the ligand or from the methanol molecule. |
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