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Poly[methano­ltetra­kis[μ(3)-5-(4-methoxy­phen­yl)pyrazole-3-carboxyl­ato(2−)]tri­copper(II)disodium(I)

The asymmetric unit of the polymeric title complex, [Cu(3)Na(2)(C(11)H(8)N(2)O(3))(4)(CH(4)O)](n), consists of two Na(I) atoms, three Cu(II) atoms, four 5-(4-methoxy­phen­yl)pyrazole-3-carboxyl­ate ligands and one methanol mol­ecule. The central Cu(II) atom is coordinated by four N atoms from four p...

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Autores principales: An, Yue, Zhou, Guang-Hua, Mu, Ping-Ping, Zhou, Xiao-Xia, Xing, Yong-Heng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915067/
https://www.ncbi.nlm.nih.gov/pubmed/21200474
http://dx.doi.org/10.1107/S1600536807064008
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author An, Yue
Zhou, Guang-Hua
Mu, Ping-Ping
Zhou, Xiao-Xia
Xing, Yong-Heng
author_facet An, Yue
Zhou, Guang-Hua
Mu, Ping-Ping
Zhou, Xiao-Xia
Xing, Yong-Heng
author_sort An, Yue
collection PubMed
description The asymmetric unit of the polymeric title complex, [Cu(3)Na(2)(C(11)H(8)N(2)O(3))(4)(CH(4)O)](n), consists of two Na(I) atoms, three Cu(II) atoms, four 5-(4-methoxy­phen­yl)pyrazole-3-carboxyl­ate ligands and one methanol mol­ecule. The central Cu(II) atom is coordinated by four N atoms from four pyrazole-3-carboxyl­ate ligands, forming a distorted tetra­hedral (CuN(4)) geometry, while each of the other two Cu(II) atoms is coordinated by two O atoms and two N atoms from the two ligands, forming a slightly distorted square-planar (CuN(2)O(2)) geometry. Each of the two Na(I) atoms is coordinated by five O atoms, forming a distorted octahedral geometry; four O atoms are from the carboxyl­ate groups of the three ligands and the remaining O atom is from the meth­oxy group of the ligand or from the methanol mol­ecule.
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spelling pubmed-29150672010-12-30 Poly[methano­ltetra­kis[μ(3)-5-(4-methoxy­phen­yl)pyrazole-3-carboxyl­ato(2−)]tri­copper(II)disodium(I) An, Yue Zhou, Guang-Hua Mu, Ping-Ping Zhou, Xiao-Xia Xing, Yong-Heng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the polymeric title complex, [Cu(3)Na(2)(C(11)H(8)N(2)O(3))(4)(CH(4)O)](n), consists of two Na(I) atoms, three Cu(II) atoms, four 5-(4-methoxy­phen­yl)pyrazole-3-carboxyl­ate ligands and one methanol mol­ecule. The central Cu(II) atom is coordinated by four N atoms from four pyrazole-3-carboxyl­ate ligands, forming a distorted tetra­hedral (CuN(4)) geometry, while each of the other two Cu(II) atoms is coordinated by two O atoms and two N atoms from the two ligands, forming a slightly distorted square-planar (CuN(2)O(2)) geometry. Each of the two Na(I) atoms is coordinated by five O atoms, forming a distorted octahedral geometry; four O atoms are from the carboxyl­ate groups of the three ligands and the remaining O atom is from the meth­oxy group of the ligand or from the methanol mol­ecule. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915067/ /pubmed/21200474 http://dx.doi.org/10.1107/S1600536807064008 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
An, Yue
Zhou, Guang-Hua
Mu, Ping-Ping
Zhou, Xiao-Xia
Xing, Yong-Heng
Poly[methano­ltetra­kis[μ(3)-5-(4-methoxy­phen­yl)pyrazole-3-carboxyl­ato(2−)]tri­copper(II)disodium(I)
title Poly[methano­ltetra­kis[μ(3)-5-(4-methoxy­phen­yl)pyrazole-3-carboxyl­ato(2−)]tri­copper(II)disodium(I)
title_full Poly[methano­ltetra­kis[μ(3)-5-(4-methoxy­phen­yl)pyrazole-3-carboxyl­ato(2−)]tri­copper(II)disodium(I)
title_fullStr Poly[methano­ltetra­kis[μ(3)-5-(4-methoxy­phen­yl)pyrazole-3-carboxyl­ato(2−)]tri­copper(II)disodium(I)
title_full_unstemmed Poly[methano­ltetra­kis[μ(3)-5-(4-methoxy­phen­yl)pyrazole-3-carboxyl­ato(2−)]tri­copper(II)disodium(I)
title_short Poly[methano­ltetra­kis[μ(3)-5-(4-methoxy­phen­yl)pyrazole-3-carboxyl­ato(2−)]tri­copper(II)disodium(I)
title_sort poly[methano­ltetra­kis[μ(3)-5-(4-methoxy­phen­yl)pyrazole-3-carboxyl­ato(2−)]tri­copper(ii)disodium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915067/
https://www.ncbi.nlm.nih.gov/pubmed/21200474
http://dx.doi.org/10.1107/S1600536807064008
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