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Poly[methanoltetrakis[μ(3)-5-(4-methoxyphenyl)pyrazole-3-carboxylato(2−)]tricopper(II)disodium(I)
The asymmetric unit of the polymeric title complex, [Cu(3)Na(2)(C(11)H(8)N(2)O(3))(4)(CH(4)O)](n), consists of two Na(I) atoms, three Cu(II) atoms, four 5-(4-methoxyphenyl)pyrazole-3-carboxylate ligands and one methanol molecule. The central Cu(II) atom is coordinated by four N atoms from four p...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2007
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915067/ https://www.ncbi.nlm.nih.gov/pubmed/21200474 http://dx.doi.org/10.1107/S1600536807064008 |
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author | An, Yue Zhou, Guang-Hua Mu, Ping-Ping Zhou, Xiao-Xia Xing, Yong-Heng |
author_facet | An, Yue Zhou, Guang-Hua Mu, Ping-Ping Zhou, Xiao-Xia Xing, Yong-Heng |
author_sort | An, Yue |
collection | PubMed |
description | The asymmetric unit of the polymeric title complex, [Cu(3)Na(2)(C(11)H(8)N(2)O(3))(4)(CH(4)O)](n), consists of two Na(I) atoms, three Cu(II) atoms, four 5-(4-methoxyphenyl)pyrazole-3-carboxylate ligands and one methanol molecule. The central Cu(II) atom is coordinated by four N atoms from four pyrazole-3-carboxylate ligands, forming a distorted tetrahedral (CuN(4)) geometry, while each of the other two Cu(II) atoms is coordinated by two O atoms and two N atoms from the two ligands, forming a slightly distorted square-planar (CuN(2)O(2)) geometry. Each of the two Na(I) atoms is coordinated by five O atoms, forming a distorted octahedral geometry; four O atoms are from the carboxylate groups of the three ligands and the remaining O atom is from the methoxy group of the ligand or from the methanol molecule. |
format | Text |
id | pubmed-2915067 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29150672010-12-30 Poly[methanoltetrakis[μ(3)-5-(4-methoxyphenyl)pyrazole-3-carboxylato(2−)]tricopper(II)disodium(I) An, Yue Zhou, Guang-Hua Mu, Ping-Ping Zhou, Xiao-Xia Xing, Yong-Heng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the polymeric title complex, [Cu(3)Na(2)(C(11)H(8)N(2)O(3))(4)(CH(4)O)](n), consists of two Na(I) atoms, three Cu(II) atoms, four 5-(4-methoxyphenyl)pyrazole-3-carboxylate ligands and one methanol molecule. The central Cu(II) atom is coordinated by four N atoms from four pyrazole-3-carboxylate ligands, forming a distorted tetrahedral (CuN(4)) geometry, while each of the other two Cu(II) atoms is coordinated by two O atoms and two N atoms from the two ligands, forming a slightly distorted square-planar (CuN(2)O(2)) geometry. Each of the two Na(I) atoms is coordinated by five O atoms, forming a distorted octahedral geometry; four O atoms are from the carboxylate groups of the three ligands and the remaining O atom is from the methoxy group of the ligand or from the methanol molecule. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915067/ /pubmed/21200474 http://dx.doi.org/10.1107/S1600536807064008 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers An, Yue Zhou, Guang-Hua Mu, Ping-Ping Zhou, Xiao-Xia Xing, Yong-Heng Poly[methanoltetrakis[μ(3)-5-(4-methoxyphenyl)pyrazole-3-carboxylato(2−)]tricopper(II)disodium(I) |
title | Poly[methanoltetrakis[μ(3)-5-(4-methoxyphenyl)pyrazole-3-carboxylato(2−)]tricopper(II)disodium(I) |
title_full | Poly[methanoltetrakis[μ(3)-5-(4-methoxyphenyl)pyrazole-3-carboxylato(2−)]tricopper(II)disodium(I) |
title_fullStr | Poly[methanoltetrakis[μ(3)-5-(4-methoxyphenyl)pyrazole-3-carboxylato(2−)]tricopper(II)disodium(I) |
title_full_unstemmed | Poly[methanoltetrakis[μ(3)-5-(4-methoxyphenyl)pyrazole-3-carboxylato(2−)]tricopper(II)disodium(I) |
title_short | Poly[methanoltetrakis[μ(3)-5-(4-methoxyphenyl)pyrazole-3-carboxylato(2−)]tricopper(II)disodium(I) |
title_sort | poly[methanoltetrakis[μ(3)-5-(4-methoxyphenyl)pyrazole-3-carboxylato(2−)]tricopper(ii)disodium(i) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915067/ https://www.ncbi.nlm.nih.gov/pubmed/21200474 http://dx.doi.org/10.1107/S1600536807064008 |
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