Monoclinic polymorph of poly[[di-μ-aqua-triaquadi-μ-oxalato-barium(II)­copper(II)] monohydrate]

A monoclinic polymorph of the title compound, {[BaCu(C(2)O(4))(2)(H(2)O)(5)]·H(2)O}(n), is reported. The structure is best described as a coordination polymer where the Cu(II) and Ba(II) centers are coordinated by five and nine O atoms, respectively, in capped quadratic antiprismatic and tetragonal...

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Detalles Bibliográficos
Autores principales: Nenwa, Justin, Belombe, Michel M., Fokwa, Boniface P. T., Dronskowski, Richard
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915069/
https://www.ncbi.nlm.nih.gov/pubmed/21200476
http://dx.doi.org/10.1107/S1600536807064525
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author Nenwa, Justin
Belombe, Michel M.
Fokwa, Boniface P. T.
Dronskowski, Richard
author_facet Nenwa, Justin
Belombe, Michel M.
Fokwa, Boniface P. T.
Dronskowski, Richard
author_sort Nenwa, Justin
collection PubMed
description A monoclinic polymorph of the title compound, {[BaCu(C(2)O(4))(2)(H(2)O)(5)]·H(2)O}(n), is reported. The structure is best described as a coordination polymer where the Cu(II) and Ba(II) centers are coordinated by five and nine O atoms, respectively, in capped quadratic antiprismatic and tetragonal pyramidal geometries. The polymerization arises due to the presence of bridging mono- and bidentate oxalate ligands as well as bridging water mol­ecules. The crystal structure is consolidated by a three-dimensional network of hydrogen bonding.
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spelling pubmed-29150692010-12-30 Monoclinic polymorph of poly[[di-μ-aqua-triaquadi-μ-oxalato-barium(II)­copper(II)] monohydrate] Nenwa, Justin Belombe, Michel M. Fokwa, Boniface P. T. Dronskowski, Richard Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers A monoclinic polymorph of the title compound, {[BaCu(C(2)O(4))(2)(H(2)O)(5)]·H(2)O}(n), is reported. The structure is best described as a coordination polymer where the Cu(II) and Ba(II) centers are coordinated by five and nine O atoms, respectively, in capped quadratic antiprismatic and tetragonal pyramidal geometries. The polymerization arises due to the presence of bridging mono- and bidentate oxalate ligands as well as bridging water mol­ecules. The crystal structure is consolidated by a three-dimensional network of hydrogen bonding. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915069/ /pubmed/21200476 http://dx.doi.org/10.1107/S1600536807064525 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Nenwa, Justin
Belombe, Michel M.
Fokwa, Boniface P. T.
Dronskowski, Richard
Monoclinic polymorph of poly[[di-μ-aqua-triaquadi-μ-oxalato-barium(II)­copper(II)] monohydrate]
title Monoclinic polymorph of poly[[di-μ-aqua-triaquadi-μ-oxalato-barium(II)­copper(II)] monohydrate]
title_full Monoclinic polymorph of poly[[di-μ-aqua-triaquadi-μ-oxalato-barium(II)­copper(II)] monohydrate]
title_fullStr Monoclinic polymorph of poly[[di-μ-aqua-triaquadi-μ-oxalato-barium(II)­copper(II)] monohydrate]
title_full_unstemmed Monoclinic polymorph of poly[[di-μ-aqua-triaquadi-μ-oxalato-barium(II)­copper(II)] monohydrate]
title_short Monoclinic polymorph of poly[[di-μ-aqua-triaquadi-μ-oxalato-barium(II)­copper(II)] monohydrate]
title_sort monoclinic polymorph of poly[[di-μ-aqua-triaquadi-μ-oxalato-barium(ii)­copper(ii)] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915069/
https://www.ncbi.nlm.nih.gov/pubmed/21200476
http://dx.doi.org/10.1107/S1600536807064525
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