(1-{2-[2-(2-Ammonio­ethyl­amino)ethyl­amino]ethyl­imino­meth­yl}-2-naphtholato-κ(4) O,N,N′,N′′)chloridocopper(II) chloride

In the square-pyramidal title complex, [CuCl(C(17)H(24)N(4)O)]Cl, the Cu(II) atom is coordinated by three N atoms [Cu—N 1.946 (2), 2.010 (2), 2.085 (3) Å], one O atom [Cu—O 1.910 (2) Å] and one apical Cl atom [Cu—Cl 2.6437 (9) Å]. The three coordinated N and one O atom are almost coplanar, with a ma...

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Detalles Bibliográficos
Autores principales: Xue, Ruiting, Niu, Meiju
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915070/
https://www.ncbi.nlm.nih.gov/pubmed/21200477
http://dx.doi.org/10.1107/S1600536807064033
Descripción
Sumario:In the square-pyramidal title complex, [CuCl(C(17)H(24)N(4)O)]Cl, the Cu(II) atom is coordinated by three N atoms [Cu—N 1.946 (2), 2.010 (2), 2.085 (3) Å], one O atom [Cu—O 1.910 (2) Å] and one apical Cl atom [Cu—Cl 2.6437 (9) Å]. The three coordinated N and one O atom are almost coplanar, with a maximum deviation of 0.0268 Å. The tetra­dentate ligand forms two five-membered (N—Cu—N) and one six-membered (N—Cu—O) chelate rings with bite angles of 84.06 (10), 85.30 (10) and 91.70 (9)°, respectively. The two N—Cu—N chelate rings are non-planar.

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