(1-{2-[2-(2-Ammonio­ethyl­amino)ethyl­amino]ethyl­imino­meth­yl}-2-naphtholato-κ(4) O,N,N′,N′′)chloridocopper(II) chloride

In the square-pyramidal title complex, [CuCl(C(17)H(24)N(4)O)]Cl, the Cu(II) atom is coordinated by three N atoms [Cu—N 1.946 (2), 2.010 (2), 2.085 (3) Å], one O atom [Cu—O 1.910 (2) Å] and one apical Cl atom [Cu—Cl 2.6437 (9) Å]. The three coordinated N and one O atom are almost coplanar, with a ma...

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Detalles Bibliográficos
Autores principales: Xue, Ruiting, Niu, Meiju
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915070/
https://www.ncbi.nlm.nih.gov/pubmed/21200477
http://dx.doi.org/10.1107/S1600536807064033
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author Xue, Ruiting
Niu, Meiju
author_facet Xue, Ruiting
Niu, Meiju
author_sort Xue, Ruiting
collection PubMed
description In the square-pyramidal title complex, [CuCl(C(17)H(24)N(4)O)]Cl, the Cu(II) atom is coordinated by three N atoms [Cu—N 1.946 (2), 2.010 (2), 2.085 (3) Å], one O atom [Cu—O 1.910 (2) Å] and one apical Cl atom [Cu—Cl 2.6437 (9) Å]. The three coordinated N and one O atom are almost coplanar, with a maximum deviation of 0.0268 Å. The tetra­dentate ligand forms two five-membered (N—Cu—N) and one six-membered (N—Cu—O) chelate rings with bite angles of 84.06 (10), 85.30 (10) and 91.70 (9)°, respectively. The two N—Cu—N chelate rings are non-planar.
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spelling pubmed-29150702010-12-30 (1-{2-[2-(2-Ammonio­ethyl­amino)ethyl­amino]ethyl­imino­meth­yl}-2-naphtholato-κ(4) O,N,N′,N′′)chloridocopper(II) chloride Xue, Ruiting Niu, Meiju Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the square-pyramidal title complex, [CuCl(C(17)H(24)N(4)O)]Cl, the Cu(II) atom is coordinated by three N atoms [Cu—N 1.946 (2), 2.010 (2), 2.085 (3) Å], one O atom [Cu—O 1.910 (2) Å] and one apical Cl atom [Cu—Cl 2.6437 (9) Å]. The three coordinated N and one O atom are almost coplanar, with a maximum deviation of 0.0268 Å. The tetra­dentate ligand forms two five-membered (N—Cu—N) and one six-membered (N—Cu—O) chelate rings with bite angles of 84.06 (10), 85.30 (10) and 91.70 (9)°, respectively. The two N—Cu—N chelate rings are non-planar. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915070/ /pubmed/21200477 http://dx.doi.org/10.1107/S1600536807064033 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Xue, Ruiting
Niu, Meiju
(1-{2-[2-(2-Ammonio­ethyl­amino)ethyl­amino]ethyl­imino­meth­yl}-2-naphtholato-κ(4) O,N,N′,N′′)chloridocopper(II) chloride
title (1-{2-[2-(2-Ammonio­ethyl­amino)ethyl­amino]ethyl­imino­meth­yl}-2-naphtholato-κ(4) O,N,N′,N′′)chloridocopper(II) chloride
title_full (1-{2-[2-(2-Ammonio­ethyl­amino)ethyl­amino]ethyl­imino­meth­yl}-2-naphtholato-κ(4) O,N,N′,N′′)chloridocopper(II) chloride
title_fullStr (1-{2-[2-(2-Ammonio­ethyl­amino)ethyl­amino]ethyl­imino­meth­yl}-2-naphtholato-κ(4) O,N,N′,N′′)chloridocopper(II) chloride
title_full_unstemmed (1-{2-[2-(2-Ammonio­ethyl­amino)ethyl­amino]ethyl­imino­meth­yl}-2-naphtholato-κ(4) O,N,N′,N′′)chloridocopper(II) chloride
title_short (1-{2-[2-(2-Ammonio­ethyl­amino)ethyl­amino]ethyl­imino­meth­yl}-2-naphtholato-κ(4) O,N,N′,N′′)chloridocopper(II) chloride
title_sort (1-{2-[2-(2-ammonio­ethyl­amino)ethyl­amino]ethyl­imino­meth­yl}-2-naphtholato-κ(4) o,n,n′,n′′)chloridocopper(ii) chloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915070/
https://www.ncbi.nlm.nih.gov/pubmed/21200477
http://dx.doi.org/10.1107/S1600536807064033
work_keys_str_mv AT xueruiting 1222ammonioethylaminoethylaminoethyliminomethyl2naphtholatok4onnnchloridocopperiichloride
AT niumeiju 1222ammonioethylaminoethylaminoethyliminomethyl2naphtholatok4onnnchloridocopperiichloride

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