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A one-dimensional ladder-like coordination polymer: poly[[hexa­aqua­bis(μ-5-nitro­benzene-1,3-dicarboxyl­ato-κ(3) O,O′,O′′)(μ-oxalato-κ(4) O,O′:O′′,O′′′)diyttrium(III)] trihydrate]

In the crystal structure of the title one-dimensional coordination polymer, [Y(2)(C(8)H(3)NO(6))(2)(C(2)O(4))(H(2)O)(6)]·3H(2)O, each Y(III) ion is bridged to its neighbours by two 5-nitro­benzene-1,3-dicarboxyl­ate (nbdc) dianions and one oxalate dianion (located on an inversion centre) to form a l...

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Detalles Bibliográficos
Autores principales: Fu, Zhong, Lin, Ying, Zhou, Yun-You, Zhang, Hong-Tao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915072/
https://www.ncbi.nlm.nih.gov/pubmed/21200480
http://dx.doi.org/10.1107/S1600536807064306
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author Fu, Zhong
Lin, Ying
Zhou, Yun-You
Zhang, Hong-Tao
author_facet Fu, Zhong
Lin, Ying
Zhou, Yun-You
Zhang, Hong-Tao
author_sort Fu, Zhong
collection PubMed
description In the crystal structure of the title one-dimensional coordination polymer, [Y(2)(C(8)H(3)NO(6))(2)(C(2)O(4))(H(2)O)(6)]·3H(2)O, each Y(III) ion is bridged to its neighbours by two 5-nitro­benzene-1,3-dicarboxyl­ate (nbdc) dianions and one oxalate dianion (located on an inversion centre) to form a ladder-like polymeric structure. The two carboxylate groups of nbdc assume different modes of coordination, one is chelating whereas the other is monodentate. Three water mol­ecules coordinate to the Y(III) ion to complete an eight-coordinate distorted dodecahedral geometry. The ladder-like polymers are assembled together by hydrogen bonding and π–π stacking [centrio–centriod distance = 3.819 (9) Å] in the crystal structure.
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spelling pubmed-29150722010-12-30 A one-dimensional ladder-like coordination polymer: poly[[hexa­aqua­bis(μ-5-nitro­benzene-1,3-dicarboxyl­ato-κ(3) O,O′,O′′)(μ-oxalato-κ(4) O,O′:O′′,O′′′)diyttrium(III)] trihydrate] Fu, Zhong Lin, Ying Zhou, Yun-You Zhang, Hong-Tao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title one-dimensional coordination polymer, [Y(2)(C(8)H(3)NO(6))(2)(C(2)O(4))(H(2)O)(6)]·3H(2)O, each Y(III) ion is bridged to its neighbours by two 5-nitro­benzene-1,3-dicarboxyl­ate (nbdc) dianions and one oxalate dianion (located on an inversion centre) to form a ladder-like polymeric structure. The two carboxylate groups of nbdc assume different modes of coordination, one is chelating whereas the other is monodentate. Three water mol­ecules coordinate to the Y(III) ion to complete an eight-coordinate distorted dodecahedral geometry. The ladder-like polymers are assembled together by hydrogen bonding and π–π stacking [centrio–centriod distance = 3.819 (9) Å] in the crystal structure. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915072/ /pubmed/21200480 http://dx.doi.org/10.1107/S1600536807064306 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Fu, Zhong
Lin, Ying
Zhou, Yun-You
Zhang, Hong-Tao
A one-dimensional ladder-like coordination polymer: poly[[hexa­aqua­bis(μ-5-nitro­benzene-1,3-dicarboxyl­ato-κ(3) O,O′,O′′)(μ-oxalato-κ(4) O,O′:O′′,O′′′)diyttrium(III)] trihydrate]
title A one-dimensional ladder-like coordination polymer: poly[[hexa­aqua­bis(μ-5-nitro­benzene-1,3-dicarboxyl­ato-κ(3) O,O′,O′′)(μ-oxalato-κ(4) O,O′:O′′,O′′′)diyttrium(III)] trihydrate]
title_full A one-dimensional ladder-like coordination polymer: poly[[hexa­aqua­bis(μ-5-nitro­benzene-1,3-dicarboxyl­ato-κ(3) O,O′,O′′)(μ-oxalato-κ(4) O,O′:O′′,O′′′)diyttrium(III)] trihydrate]
title_fullStr A one-dimensional ladder-like coordination polymer: poly[[hexa­aqua­bis(μ-5-nitro­benzene-1,3-dicarboxyl­ato-κ(3) O,O′,O′′)(μ-oxalato-κ(4) O,O′:O′′,O′′′)diyttrium(III)] trihydrate]
title_full_unstemmed A one-dimensional ladder-like coordination polymer: poly[[hexa­aqua­bis(μ-5-nitro­benzene-1,3-dicarboxyl­ato-κ(3) O,O′,O′′)(μ-oxalato-κ(4) O,O′:O′′,O′′′)diyttrium(III)] trihydrate]
title_short A one-dimensional ladder-like coordination polymer: poly[[hexa­aqua­bis(μ-5-nitro­benzene-1,3-dicarboxyl­ato-κ(3) O,O′,O′′)(μ-oxalato-κ(4) O,O′:O′′,O′′′)diyttrium(III)] trihydrate]
title_sort one-dimensional ladder-like coordination polymer: poly[[hexa­aqua­bis(μ-5-nitro­benzene-1,3-dicarboxyl­ato-κ(3) o,o′,o′′)(μ-oxalato-κ(4) o,o′:o′′,o′′′)diyttrium(iii)] trihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915072/
https://www.ncbi.nlm.nih.gov/pubmed/21200480
http://dx.doi.org/10.1107/S1600536807064306
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