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A one-dimensional ladder-like coordination polymer: poly[[hexaaquabis(μ-5-nitrobenzene-1,3-dicarboxylato-κ(3) O,O′,O′′)(μ-oxalato-κ(4) O,O′:O′′,O′′′)diyttrium(III)] trihydrate]
In the crystal structure of the title one-dimensional coordination polymer, [Y(2)(C(8)H(3)NO(6))(2)(C(2)O(4))(H(2)O)(6)]·3H(2)O, each Y(III) ion is bridged to its neighbours by two 5-nitrobenzene-1,3-dicarboxylate (nbdc) dianions and one oxalate dianion (located on an inversion centre) to form a l...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915072/ https://www.ncbi.nlm.nih.gov/pubmed/21200480 http://dx.doi.org/10.1107/S1600536807064306 |
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author | Fu, Zhong Lin, Ying Zhou, Yun-You Zhang, Hong-Tao |
author_facet | Fu, Zhong Lin, Ying Zhou, Yun-You Zhang, Hong-Tao |
author_sort | Fu, Zhong |
collection | PubMed |
description | In the crystal structure of the title one-dimensional coordination polymer, [Y(2)(C(8)H(3)NO(6))(2)(C(2)O(4))(H(2)O)(6)]·3H(2)O, each Y(III) ion is bridged to its neighbours by two 5-nitrobenzene-1,3-dicarboxylate (nbdc) dianions and one oxalate dianion (located on an inversion centre) to form a ladder-like polymeric structure. The two carboxylate groups of nbdc assume different modes of coordination, one is chelating whereas the other is monodentate. Three water molecules coordinate to the Y(III) ion to complete an eight-coordinate distorted dodecahedral geometry. The ladder-like polymers are assembled together by hydrogen bonding and π–π stacking [centrio–centriod distance = 3.819 (9) Å] in the crystal structure. |
format | Text |
id | pubmed-2915072 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29150722010-12-30 A one-dimensional ladder-like coordination polymer: poly[[hexaaquabis(μ-5-nitrobenzene-1,3-dicarboxylato-κ(3) O,O′,O′′)(μ-oxalato-κ(4) O,O′:O′′,O′′′)diyttrium(III)] trihydrate] Fu, Zhong Lin, Ying Zhou, Yun-You Zhang, Hong-Tao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title one-dimensional coordination polymer, [Y(2)(C(8)H(3)NO(6))(2)(C(2)O(4))(H(2)O)(6)]·3H(2)O, each Y(III) ion is bridged to its neighbours by two 5-nitrobenzene-1,3-dicarboxylate (nbdc) dianions and one oxalate dianion (located on an inversion centre) to form a ladder-like polymeric structure. The two carboxylate groups of nbdc assume different modes of coordination, one is chelating whereas the other is monodentate. Three water molecules coordinate to the Y(III) ion to complete an eight-coordinate distorted dodecahedral geometry. The ladder-like polymers are assembled together by hydrogen bonding and π–π stacking [centrio–centriod distance = 3.819 (9) Å] in the crystal structure. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915072/ /pubmed/21200480 http://dx.doi.org/10.1107/S1600536807064306 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Fu, Zhong Lin, Ying Zhou, Yun-You Zhang, Hong-Tao A one-dimensional ladder-like coordination polymer: poly[[hexaaquabis(μ-5-nitrobenzene-1,3-dicarboxylato-κ(3) O,O′,O′′)(μ-oxalato-κ(4) O,O′:O′′,O′′′)diyttrium(III)] trihydrate] |
title | A one-dimensional ladder-like coordination polymer: poly[[hexaaquabis(μ-5-nitrobenzene-1,3-dicarboxylato-κ(3)
O,O′,O′′)(μ-oxalato-κ(4)
O,O′:O′′,O′′′)diyttrium(III)] trihydrate] |
title_full | A one-dimensional ladder-like coordination polymer: poly[[hexaaquabis(μ-5-nitrobenzene-1,3-dicarboxylato-κ(3)
O,O′,O′′)(μ-oxalato-κ(4)
O,O′:O′′,O′′′)diyttrium(III)] trihydrate] |
title_fullStr | A one-dimensional ladder-like coordination polymer: poly[[hexaaquabis(μ-5-nitrobenzene-1,3-dicarboxylato-κ(3)
O,O′,O′′)(μ-oxalato-κ(4)
O,O′:O′′,O′′′)diyttrium(III)] trihydrate] |
title_full_unstemmed | A one-dimensional ladder-like coordination polymer: poly[[hexaaquabis(μ-5-nitrobenzene-1,3-dicarboxylato-κ(3)
O,O′,O′′)(μ-oxalato-κ(4)
O,O′:O′′,O′′′)diyttrium(III)] trihydrate] |
title_short | A one-dimensional ladder-like coordination polymer: poly[[hexaaquabis(μ-5-nitrobenzene-1,3-dicarboxylato-κ(3)
O,O′,O′′)(μ-oxalato-κ(4)
O,O′:O′′,O′′′)diyttrium(III)] trihydrate] |
title_sort | one-dimensional ladder-like coordination polymer: poly[[hexaaquabis(μ-5-nitrobenzene-1,3-dicarboxylato-κ(3)
o,o′,o′′)(μ-oxalato-κ(4)
o,o′:o′′,o′′′)diyttrium(iii)] trihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915072/ https://www.ncbi.nlm.nih.gov/pubmed/21200480 http://dx.doi.org/10.1107/S1600536807064306 |
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