(Piperazin-1-ium-κN (4))tris­(thio­cyanato-κN)zinc(II)

Hydro­thermal reaction of NaSCN, piperazine, Zn(II) and 2,6-naphthalenedicarboxylic acid in aqueous solutions gave rise to the title complex, [Zn(NCS)(3)(C(4)H(11)N(2))]. The Zn(II) atom is four-coordinate with distorted tetra­hedral geometry and lies in a mirror plane. N—H⋯S hydrogen bonds assemble...

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Detalles Bibliográficos
Autores principales: He, Xiang, Liu, Hong-Jiang, Li, Ming-Xing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915073/
https://www.ncbi.nlm.nih.gov/pubmed/21200481
http://dx.doi.org/10.1107/S1600536807065087
Descripción
Sumario:Hydro­thermal reaction of NaSCN, piperazine, Zn(II) and 2,6-naphthalenedicarboxylic acid in aqueous solutions gave rise to the title complex, [Zn(NCS)(3)(C(4)H(11)N(2))]. The Zn(II) atom is four-coordinate with distorted tetra­hedral geometry and lies in a mirror plane. N—H⋯S hydrogen bonds assemble the mol­ecules to form a three-dimensional framework.

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