(Piperazin-1-ium-κN (4))tris­(thio­cyanato-κN)zinc(II)

Hydro­thermal reaction of NaSCN, piperazine, Zn(II) and 2,6-naphthalenedicarboxylic acid in aqueous solutions gave rise to the title complex, [Zn(NCS)(3)(C(4)H(11)N(2))]. The Zn(II) atom is four-coordinate with distorted tetra­hedral geometry and lies in a mirror plane. N—H⋯S hydrogen bonds assemble...

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Detalles Bibliográficos
Autores principales: He, Xiang, Liu, Hong-Jiang, Li, Ming-Xing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915073/
https://www.ncbi.nlm.nih.gov/pubmed/21200481
http://dx.doi.org/10.1107/S1600536807065087
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author He, Xiang
Liu, Hong-Jiang
Li, Ming-Xing
author_facet He, Xiang
Liu, Hong-Jiang
Li, Ming-Xing
author_sort He, Xiang
collection PubMed
description Hydro­thermal reaction of NaSCN, piperazine, Zn(II) and 2,6-naphthalenedicarboxylic acid in aqueous solutions gave rise to the title complex, [Zn(NCS)(3)(C(4)H(11)N(2))]. The Zn(II) atom is four-coordinate with distorted tetra­hedral geometry and lies in a mirror plane. N—H⋯S hydrogen bonds assemble the mol­ecules to form a three-dimensional framework.
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spelling pubmed-29150732010-12-30 (Piperazin-1-ium-κN (4))tris­(thio­cyanato-κN)zinc(II) He, Xiang Liu, Hong-Jiang Li, Ming-Xing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Hydro­thermal reaction of NaSCN, piperazine, Zn(II) and 2,6-naphthalenedicarboxylic acid in aqueous solutions gave rise to the title complex, [Zn(NCS)(3)(C(4)H(11)N(2))]. The Zn(II) atom is four-coordinate with distorted tetra­hedral geometry and lies in a mirror plane. N—H⋯S hydrogen bonds assemble the mol­ecules to form a three-dimensional framework. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915073/ /pubmed/21200481 http://dx.doi.org/10.1107/S1600536807065087 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
He, Xiang
Liu, Hong-Jiang
Li, Ming-Xing
(Piperazin-1-ium-κN (4))tris­(thio­cyanato-κN)zinc(II)
title (Piperazin-1-ium-κN (4))tris­(thio­cyanato-κN)zinc(II)
title_full (Piperazin-1-ium-κN (4))tris­(thio­cyanato-κN)zinc(II)
title_fullStr (Piperazin-1-ium-κN (4))tris­(thio­cyanato-κN)zinc(II)
title_full_unstemmed (Piperazin-1-ium-κN (4))tris­(thio­cyanato-κN)zinc(II)
title_short (Piperazin-1-ium-κN (4))tris­(thio­cyanato-κN)zinc(II)
title_sort (piperazin-1-ium-κn (4))tris­(thio­cyanato-κn)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915073/
https://www.ncbi.nlm.nih.gov/pubmed/21200481
http://dx.doi.org/10.1107/S1600536807065087
work_keys_str_mv AT hexiang piperazin1iumkn4tristhiocyanatoknzincii
AT liuhongjiang piperazin1iumkn4tristhiocyanatoknzincii
AT limingxing piperazin1iumkn4tristhiocyanatoknzincii

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