Salicylato[tris­(N-methyl­benzimidazol-2-ylmeth­yl)amine]zinc(II) perchlorate dimethyl­formamide sesquisolvate

In the title complex, [Zn(C(7)H(5)O(3))(C(27)H(27)N(7))]ClO(4)·1.5C(3)H(7)NO, the Zn(II) atom is five-coordinated by four N atoms from a tris­(N-methyl­benzimidazol-2-ylmeth­yl)amine ligand and one O atom from a salicylate ligand in a distorted trigonal-bipyramidal geometry (τ parameter = 0.84), wit...

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Detalles Bibliográficos
Autores principales: Wu, Huilu, Yun, Ruirui, Ding, Jian, Yuan, Jingkun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915077/
https://www.ncbi.nlm.nih.gov/pubmed/21200485
http://dx.doi.org/10.1107/S1600536807064902
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author Wu, Huilu
Yun, Ruirui
Ding, Jian
Yuan, Jingkun
author_facet Wu, Huilu
Yun, Ruirui
Ding, Jian
Yuan, Jingkun
author_sort Wu, Huilu
collection PubMed
description In the title complex, [Zn(C(7)H(5)O(3))(C(27)H(27)N(7))]ClO(4)·1.5C(3)H(7)NO, the Zn(II) atom is five-coordinated by four N atoms from a tris­(N-methyl­benzimidazol-2-ylmeth­yl)amine ligand and one O atom from a salicylate ligand in a distorted trigonal-bipyramidal geometry (τ parameter = 0.84), with approximate mol­ecular C (3) symmetry. One dimethyl­formamide mol­ecule lies on a general position and is disordered over two coplanar orientations with equal occupancy. A second dimethyl­formamide mol­ecule is disordered about a twofold rotation axis.
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spelling pubmed-29150772010-12-30 Salicylato[tris­(N-methyl­benzimidazol-2-ylmeth­yl)amine]zinc(II) perchlorate dimethyl­formamide sesquisolvate Wu, Huilu Yun, Ruirui Ding, Jian Yuan, Jingkun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(C(7)H(5)O(3))(C(27)H(27)N(7))]ClO(4)·1.5C(3)H(7)NO, the Zn(II) atom is five-coordinated by four N atoms from a tris­(N-methyl­benzimidazol-2-ylmeth­yl)amine ligand and one O atom from a salicylate ligand in a distorted trigonal-bipyramidal geometry (τ parameter = 0.84), with approximate mol­ecular C (3) symmetry. One dimethyl­formamide mol­ecule lies on a general position and is disordered over two coplanar orientations with equal occupancy. A second dimethyl­formamide mol­ecule is disordered about a twofold rotation axis. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915077/ /pubmed/21200485 http://dx.doi.org/10.1107/S1600536807064902 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Wu, Huilu
Yun, Ruirui
Ding, Jian
Yuan, Jingkun
Salicylato[tris­(N-methyl­benzimidazol-2-ylmeth­yl)amine]zinc(II) perchlorate dimethyl­formamide sesquisolvate
title Salicylato[tris­(N-methyl­benzimidazol-2-ylmeth­yl)amine]zinc(II) perchlorate dimethyl­formamide sesquisolvate
title_full Salicylato[tris­(N-methyl­benzimidazol-2-ylmeth­yl)amine]zinc(II) perchlorate dimethyl­formamide sesquisolvate
title_fullStr Salicylato[tris­(N-methyl­benzimidazol-2-ylmeth­yl)amine]zinc(II) perchlorate dimethyl­formamide sesquisolvate
title_full_unstemmed Salicylato[tris­(N-methyl­benzimidazol-2-ylmeth­yl)amine]zinc(II) perchlorate dimethyl­formamide sesquisolvate
title_short Salicylato[tris­(N-methyl­benzimidazol-2-ylmeth­yl)amine]zinc(II) perchlorate dimethyl­formamide sesquisolvate
title_sort salicylato[tris­(n-methyl­benzimidazol-2-ylmeth­yl)amine]zinc(ii) perchlorate dimethyl­formamide sesquisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915077/
https://www.ncbi.nlm.nih.gov/pubmed/21200485
http://dx.doi.org/10.1107/S1600536807064902
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AT dingjian salicylatotrisnmethylbenzimidazol2ylmethylaminezinciiperchloratedimethylformamidesesquisolvate
AT yuanjingkun salicylatotrisnmethylbenzimidazol2ylmethylaminezinciiperchloratedimethylformamidesesquisolvate

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