(μ-4-Bromo-2-{1-[2-(dimethyl­amino)ethyl­imino]eth­yl}phenolato)bis­[ethyl­zinc(II)]

The title complex, [Zn(2)(C(2)H(5))(2)(C(12)H(16)BrN(2)O)(2)], is dimeric, bridged through the O atoms of the phenolate anions. The molecule lies on a crystallographic twofold rotation axis. Each Zn atom is penta­coordinated by two N atoms and two bridging O atoms of the tridentate salicylideneimina...

Descripción completa

Detalles Bibliográficos
Autores principales: Hung, Wen-Chou, Lai, Shu-Ling, Lin, Chu-Chieh
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915078/
https://www.ncbi.nlm.nih.gov/pubmed/21200486
http://dx.doi.org/10.1107/S1600536807065208
_version_ 1782184854654287872
author Hung, Wen-Chou
Lai, Shu-Ling
Lin, Chu-Chieh
author_facet Hung, Wen-Chou
Lai, Shu-Ling
Lin, Chu-Chieh
author_sort Hung, Wen-Chou
collection PubMed
description The title complex, [Zn(2)(C(2)H(5))(2)(C(12)H(16)BrN(2)O)(2)], is dimeric, bridged through the O atoms of the phenolate anions. The molecule lies on a crystallographic twofold rotation axis. Each Zn atom is penta­coordinated by two N atoms and two bridging O atoms of the tridentate salicylideneiminate ligands and one C atom from an ethyl group, forming a distorted square-pyramidal environment.
format Text
id pubmed-2915078
institution National Center for Biotechnology Information
language English
publishDate 2007
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29150782010-12-30 (μ-4-Bromo-2-{1-[2-(dimethyl­amino)ethyl­imino]eth­yl}phenolato)bis­[ethyl­zinc(II)] Hung, Wen-Chou Lai, Shu-Ling Lin, Chu-Chieh Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Zn(2)(C(2)H(5))(2)(C(12)H(16)BrN(2)O)(2)], is dimeric, bridged through the O atoms of the phenolate anions. The molecule lies on a crystallographic twofold rotation axis. Each Zn atom is penta­coordinated by two N atoms and two bridging O atoms of the tridentate salicylideneiminate ligands and one C atom from an ethyl group, forming a distorted square-pyramidal environment. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915078/ /pubmed/21200486 http://dx.doi.org/10.1107/S1600536807065208 Text en © Hung et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hung, Wen-Chou
Lai, Shu-Ling
Lin, Chu-Chieh
(μ-4-Bromo-2-{1-[2-(dimethyl­amino)ethyl­imino]eth­yl}phenolato)bis­[ethyl­zinc(II)]
title (μ-4-Bromo-2-{1-[2-(dimethyl­amino)ethyl­imino]eth­yl}phenolato)bis­[ethyl­zinc(II)]
title_full (μ-4-Bromo-2-{1-[2-(dimethyl­amino)ethyl­imino]eth­yl}phenolato)bis­[ethyl­zinc(II)]
title_fullStr (μ-4-Bromo-2-{1-[2-(dimethyl­amino)ethyl­imino]eth­yl}phenolato)bis­[ethyl­zinc(II)]
title_full_unstemmed (μ-4-Bromo-2-{1-[2-(dimethyl­amino)ethyl­imino]eth­yl}phenolato)bis­[ethyl­zinc(II)]
title_short (μ-4-Bromo-2-{1-[2-(dimethyl­amino)ethyl­imino]eth­yl}phenolato)bis­[ethyl­zinc(II)]
title_sort (μ-4-bromo-2-{1-[2-(dimethyl­amino)ethyl­imino]eth­yl}phenolato)bis­[ethyl­zinc(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915078/
https://www.ncbi.nlm.nih.gov/pubmed/21200486
http://dx.doi.org/10.1107/S1600536807065208
work_keys_str_mv AT hungwenchou m4bromo212dimethylaminoethyliminoethylphenolatobisethylzincii
AT laishuling m4bromo212dimethylaminoethyliminoethylphenolatobisethylzincii
AT linchuchieh m4bromo212dimethylaminoethyliminoethylphenolatobisethylzincii

Ejemplares similares