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Poly[bis(μ(2)-5-n-butyltetrazolato-κ(2) N (1):N (4))zinc(II)]
In the title complex, [Zn(C(5)H(9)N(4))(2)](n), the Zn(II) center is coordinated by four N atoms of different tetrazolate ligands with a slightly distorted tetrahedral geometry [Zn—N distances and N—Zn—N angles are in the ranges 1.991 (2)–2.007 (2) Å and 104.22 (8)–116.13 (8)°, respectively]. Each...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915080/ https://www.ncbi.nlm.nih.gov/pubmed/21200489 http://dx.doi.org/10.1107/S160053680706518X |
Sumario: | In the title complex, [Zn(C(5)H(9)N(4))(2)](n), the Zn(II) center is coordinated by four N atoms of different tetrazolate ligands with a slightly distorted tetrahedral geometry [Zn—N distances and N—Zn—N angles are in the ranges 1.991 (2)–2.007 (2) Å and 104.22 (8)–116.13 (8)°, respectively]. Each ligand links two Zn(II) atoms through its 1- and 4-position tetrazole N atoms, forming a single, fully connected three-dimensional framework with a diamond-like topology. In the crystal structure, the Zn⋯Zn separations across each tetrazole unit are 6.115 (2) and 6.134 (2) Å and the Zn⋯Zn⋯Zn angles are in the range 107.77 (8)–116.83 (8)°. |
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