Poly[bis­(μ(2)-5-n-butyl­tetra­zolato-κ(2) N (1):N (4))zinc(II)]

In the title complex, [Zn(C(5)H(9)N(4))(2)](n), the Zn(II) center is coordinated by four N atoms of different tetra­zolate ligands with a slightly distorted tetra­hedral geometry [Zn—N distances and N—Zn—N angles are in the ranges 1.991 (2)–2.007 (2) Å and 104.22 (8)–116.13 (8)°, respectively]. Each...

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Detalles Bibliográficos
Autores principales: Tong, Xiao-Lan, Liu, Hao, Yu, Qun, Li, Jian-Rong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915080/
https://www.ncbi.nlm.nih.gov/pubmed/21200489
http://dx.doi.org/10.1107/S160053680706518X
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author Tong, Xiao-Lan
Liu, Hao
Yu, Qun
Li, Jian-Rong
author_facet Tong, Xiao-Lan
Liu, Hao
Yu, Qun
Li, Jian-Rong
author_sort Tong, Xiao-Lan
collection PubMed
description In the title complex, [Zn(C(5)H(9)N(4))(2)](n), the Zn(II) center is coordinated by four N atoms of different tetra­zolate ligands with a slightly distorted tetra­hedral geometry [Zn—N distances and N—Zn—N angles are in the ranges 1.991 (2)–2.007 (2) Å and 104.22 (8)–116.13 (8)°, respectively]. Each ligand links two Zn(II) atoms through its 1- and 4-position tetra­zole N atoms, forming a single, fully connected three-dimensional framework with a diamond-like topology. In the crystal structure, the Zn⋯Zn separations across each tetra­zole unit are 6.115 (2) and 6.134 (2) Å and the Zn⋯Zn⋯Zn angles are in the range 107.77 (8)–116.83 (8)°.
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spelling pubmed-29150802010-12-30 Poly[bis­(μ(2)-5-n-butyl­tetra­zolato-κ(2) N (1):N (4))zinc(II)] Tong, Xiao-Lan Liu, Hao Yu, Qun Li, Jian-Rong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(C(5)H(9)N(4))(2)](n), the Zn(II) center is coordinated by four N atoms of different tetra­zolate ligands with a slightly distorted tetra­hedral geometry [Zn—N distances and N—Zn—N angles are in the ranges 1.991 (2)–2.007 (2) Å and 104.22 (8)–116.13 (8)°, respectively]. Each ligand links two Zn(II) atoms through its 1- and 4-position tetra­zole N atoms, forming a single, fully connected three-dimensional framework with a diamond-like topology. In the crystal structure, the Zn⋯Zn separations across each tetra­zole unit are 6.115 (2) and 6.134 (2) Å and the Zn⋯Zn⋯Zn angles are in the range 107.77 (8)–116.83 (8)°. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915080/ /pubmed/21200489 http://dx.doi.org/10.1107/S160053680706518X Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Tong, Xiao-Lan
Liu, Hao
Yu, Qun
Li, Jian-Rong
Poly[bis­(μ(2)-5-n-butyl­tetra­zolato-κ(2) N (1):N (4))zinc(II)]
title Poly[bis­(μ(2)-5-n-butyl­tetra­zolato-κ(2) N (1):N (4))zinc(II)]
title_full Poly[bis­(μ(2)-5-n-butyl­tetra­zolato-κ(2) N (1):N (4))zinc(II)]
title_fullStr Poly[bis­(μ(2)-5-n-butyl­tetra­zolato-κ(2) N (1):N (4))zinc(II)]
title_full_unstemmed Poly[bis­(μ(2)-5-n-butyl­tetra­zolato-κ(2) N (1):N (4))zinc(II)]
title_short Poly[bis­(μ(2)-5-n-butyl­tetra­zolato-κ(2) N (1):N (4))zinc(II)]
title_sort poly[bis­(μ(2)-5-n-butyl­tetra­zolato-κ(2) n (1):n (4))zinc(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915080/
https://www.ncbi.nlm.nih.gov/pubmed/21200489
http://dx.doi.org/10.1107/S160053680706518X
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AT liuhao polybism25nbutyltetrazolatok2n1n4zincii
AT yuqun polybism25nbutyltetrazolatok2n1n4zincii
AT lijianrong polybism25nbutyltetrazolatok2n1n4zincii

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