catena-Poly[[bis­(1H-benzimidazole-κN (3))palladium(II)]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)]

In the title compound, [Pd(C(8)H(4)O(4))(C(7)H(6)N(2))(2)](n), the Pd atom is tetra­coordinated by two carboxyl­ate O atoms from two benzene-1,4-dicarboxyl­ate (bdc) dianions and two N atoms from two benzimidazole ligands, resulting in a slightly distorted tetra­hedral PdO(2)N(2) geometry. The bdc l...

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Detalles Bibliográficos
Autores principales: Meng, Qingguo, Wang, Lintong, Liu, Yanzhen, Pang, Yan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915081/
https://www.ncbi.nlm.nih.gov/pubmed/21200490
http://dx.doi.org/10.1107/S1600536807065051
Descripción
Sumario:In the title compound, [Pd(C(8)H(4)O(4))(C(7)H(6)N(2))(2)](n), the Pd atom is tetra­coordinated by two carboxyl­ate O atoms from two benzene-1,4-dicarboxyl­ate (bdc) dianions and two N atoms from two benzimidazole ligands, resulting in a slightly distorted tetra­hedral PdO(2)N(2) geometry. The bdc ligand acts as a bridge, linking the Pd atoms into a chain. Inter-chain N—H⋯O hydrogen bonds help to stabilize the crystal structure.

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