catena-Poly[[bis­(1H-benzimidazole-κN (3))palladium(II)]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)]

In the title compound, [Pd(C(8)H(4)O(4))(C(7)H(6)N(2))(2)](n), the Pd atom is tetra­coordinated by two carboxyl­ate O atoms from two benzene-1,4-dicarboxyl­ate (bdc) dianions and two N atoms from two benzimidazole ligands, resulting in a slightly distorted tetra­hedral PdO(2)N(2) geometry. The bdc l...

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Detalles Bibliográficos
Autores principales: Meng, Qingguo, Wang, Lintong, Liu, Yanzhen, Pang, Yan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915081/
https://www.ncbi.nlm.nih.gov/pubmed/21200490
http://dx.doi.org/10.1107/S1600536807065051
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author Meng, Qingguo
Wang, Lintong
Liu, Yanzhen
Pang, Yan
author_facet Meng, Qingguo
Wang, Lintong
Liu, Yanzhen
Pang, Yan
author_sort Meng, Qingguo
collection PubMed
description In the title compound, [Pd(C(8)H(4)O(4))(C(7)H(6)N(2))(2)](n), the Pd atom is tetra­coordinated by two carboxyl­ate O atoms from two benzene-1,4-dicarboxyl­ate (bdc) dianions and two N atoms from two benzimidazole ligands, resulting in a slightly distorted tetra­hedral PdO(2)N(2) geometry. The bdc ligand acts as a bridge, linking the Pd atoms into a chain. Inter-chain N—H⋯O hydrogen bonds help to stabilize the crystal structure.
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spelling pubmed-29150812010-12-30 catena-Poly[[bis­(1H-benzimidazole-κN (3))palladium(II)]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)] Meng, Qingguo Wang, Lintong Liu, Yanzhen Pang, Yan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(C(8)H(4)O(4))(C(7)H(6)N(2))(2)](n), the Pd atom is tetra­coordinated by two carboxyl­ate O atoms from two benzene-1,4-dicarboxyl­ate (bdc) dianions and two N atoms from two benzimidazole ligands, resulting in a slightly distorted tetra­hedral PdO(2)N(2) geometry. The bdc ligand acts as a bridge, linking the Pd atoms into a chain. Inter-chain N—H⋯O hydrogen bonds help to stabilize the crystal structure. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915081/ /pubmed/21200490 http://dx.doi.org/10.1107/S1600536807065051 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Meng, Qingguo
Wang, Lintong
Liu, Yanzhen
Pang, Yan
catena-Poly[[bis­(1H-benzimidazole-κN (3))palladium(II)]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)]
title catena-Poly[[bis­(1H-benzimidazole-κN (3))palladium(II)]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)]
title_full catena-Poly[[bis­(1H-benzimidazole-κN (3))palladium(II)]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)]
title_fullStr catena-Poly[[bis­(1H-benzimidazole-κN (3))palladium(II)]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)]
title_full_unstemmed catena-Poly[[bis­(1H-benzimidazole-κN (3))palladium(II)]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)]
title_short catena-Poly[[bis­(1H-benzimidazole-κN (3))palladium(II)]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)]
title_sort catena-poly[[bis­(1h-benzimidazole-κn (3))palladium(ii)]-μ-benzene-1,4-dicarboxyl­ato-κ(2) o (1):o (4)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915081/
https://www.ncbi.nlm.nih.gov/pubmed/21200490
http://dx.doi.org/10.1107/S1600536807065051
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