[1,2-Bis(diisopropyl­phosphino)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′]dichloridomercury(II)

In the title complex, [HgCl(2)(C(14)H(38)B(10)P(2))], the Hg(II) atom is in a distorted HgCl(2)P(2) tetra­hedral coordination environment. The chelation of the Hg atom by two P atoms and two C atoms from the carborane skeleton results in a nearly planar five-membered ring.

Detalles Bibliográficos
Autores principales: Su, Fangfang, Guo, Qingliang, Dou, Jianmin, Li, Dacheng, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915082/
https://www.ncbi.nlm.nih.gov/pubmed/21200491
http://dx.doi.org/10.1107/S1600536807065130
Descripción
Sumario:In the title complex, [HgCl(2)(C(14)H(38)B(10)P(2))], the Hg(II) atom is in a distorted HgCl(2)P(2) tetra­hedral coordination environment. The chelation of the Hg atom by two P atoms and two C atoms from the carborane skeleton results in a nearly planar five-membered ring.

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