[1,2-Bis(diisopropyl­phosphino)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′]dichloridomercury(II)

In the title complex, [HgCl(2)(C(14)H(38)B(10)P(2))], the Hg(II) atom is in a distorted HgCl(2)P(2) tetra­hedral coordination environment. The chelation of the Hg atom by two P atoms and two C atoms from the carborane skeleton results in a nearly planar five-membered ring.

Detalles Bibliográficos
Autores principales: Su, Fangfang, Guo, Qingliang, Dou, Jianmin, Li, Dacheng, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915082/
https://www.ncbi.nlm.nih.gov/pubmed/21200491
http://dx.doi.org/10.1107/S1600536807065130
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author Su, Fangfang
Guo, Qingliang
Dou, Jianmin
Li, Dacheng
Wang, Daqi
author_facet Su, Fangfang
Guo, Qingliang
Dou, Jianmin
Li, Dacheng
Wang, Daqi
author_sort Su, Fangfang
collection PubMed
description In the title complex, [HgCl(2)(C(14)H(38)B(10)P(2))], the Hg(II) atom is in a distorted HgCl(2)P(2) tetra­hedral coordination environment. The chelation of the Hg atom by two P atoms and two C atoms from the carborane skeleton results in a nearly planar five-membered ring.
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spelling pubmed-29150822010-12-30 [1,2-Bis(diisopropyl­phosphino)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′]dichloridomercury(II) Su, Fangfang Guo, Qingliang Dou, Jianmin Li, Dacheng Wang, Daqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [HgCl(2)(C(14)H(38)B(10)P(2))], the Hg(II) atom is in a distorted HgCl(2)P(2) tetra­hedral coordination environment. The chelation of the Hg atom by two P atoms and two C atoms from the carborane skeleton results in a nearly planar five-membered ring. International Union of Crystallography 2007-12-06 /pmc/articles/PMC2915082/ /pubmed/21200491 http://dx.doi.org/10.1107/S1600536807065130 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Su, Fangfang
Guo, Qingliang
Dou, Jianmin
Li, Dacheng
Wang, Daqi
[1,2-Bis(diisopropyl­phosphino)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′]dichloridomercury(II)
title [1,2-Bis(diisopropyl­phosphino)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′]dichloridomercury(II)
title_full [1,2-Bis(diisopropyl­phosphino)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′]dichloridomercury(II)
title_fullStr [1,2-Bis(diisopropyl­phosphino)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′]dichloridomercury(II)
title_full_unstemmed [1,2-Bis(diisopropyl­phosphino)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′]dichloridomercury(II)
title_short [1,2-Bis(diisopropyl­phosphino)-1,2-dicarba-closo-dodeca­borane-κ(2) P,P′]dichloridomercury(II)
title_sort [1,2-bis(diisopropyl­phosphino)-1,2-dicarba-closo-dodeca­borane-κ(2) p,p′]dichloridomercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915082/
https://www.ncbi.nlm.nih.gov/pubmed/21200491
http://dx.doi.org/10.1107/S1600536807065130
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AT doujianmin 12bisdiisopropylphosphino12dicarbaclosododecaboranek2ppdichloridomercuryii
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