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Redetermination of poly[aquadi-μ(3)-oxydiacetato-dicopper(II)]
The title complex, [Cu(2)(C(4)H(4)O(5))(2)(H(2)O)](n), has a two-dimensional layer structure. The Cu atom has a distorted octahedral (CuO(6)) environment and is coordinated by four carboxylate group O atoms from three different oxydiacetate ligands in a planar arrangement and one half-occupancy wa...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915090/ https://www.ncbi.nlm.nih.gov/pubmed/21200501 http://dx.doi.org/10.1107/S1600536807065725 |
Sumario: | The title complex, [Cu(2)(C(4)H(4)O(5))(2)(H(2)O)](n), has a two-dimensional layer structure. The Cu atom has a distorted octahedral (CuO(6)) environment and is coordinated by four carboxylate group O atoms from three different oxydiacetate ligands in a planar arrangement and one half-occupancy water molecule and an ether O atom in the axial positions. In the crystal structure, weak intra- and intermolecular O—H⋯O hydrogen bonds help to stabilize the crystal packing. The structure has already been published [Whitlow & Davey (1975 ▶). J. Chem. Soc. Dalton. Trans. pp. 1228–1232]; this redetermination reports the structure with higher precision. |
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