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Redetermination of poly[aquadi-μ(3)-oxy­diacetato-dicopper(II)]

The title complex, [Cu(2)(C(4)H(4)O(5))(2)(H(2)O)](n), has a two-dimensional layer structure. The Cu atom has a distorted octa­hedral (CuO(6)) environment and is coordinated by four carboxyl­ate group O atoms from three different oxydiacetate ligands in a planar arrangement and one half-occupancy wa...

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Detalles Bibliográficos
Autor principal: Guo, Ming-Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915090/
https://www.ncbi.nlm.nih.gov/pubmed/21200501
http://dx.doi.org/10.1107/S1600536807065725
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author Guo, Ming-Lin
author_facet Guo, Ming-Lin
author_sort Guo, Ming-Lin
collection PubMed
description The title complex, [Cu(2)(C(4)H(4)O(5))(2)(H(2)O)](n), has a two-dimensional layer structure. The Cu atom has a distorted octa­hedral (CuO(6)) environment and is coordinated by four carboxyl­ate group O atoms from three different oxydiacetate ligands in a planar arrangement and one half-occupancy water mol­ecule and an ether O atom in the axial positions. In the crystal structure, weak intra- and inter­molecular O—H⋯O hydrogen bonds help to stabilize the crystal packing. The structure has already been published [Whitlow & Davey (1975 ▶). J. Chem. Soc. Dalton. Trans. pp. 1228–1232]; this redetermination reports the structure with higher precision.
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spelling pubmed-29150902010-12-30 Redetermination of poly[aquadi-μ(3)-oxy­diacetato-dicopper(II)] Guo, Ming-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(2)(C(4)H(4)O(5))(2)(H(2)O)](n), has a two-dimensional layer structure. The Cu atom has a distorted octa­hedral (CuO(6)) environment and is coordinated by four carboxyl­ate group O atoms from three different oxydiacetate ligands in a planar arrangement and one half-occupancy water mol­ecule and an ether O atom in the axial positions. In the crystal structure, weak intra- and inter­molecular O—H⋯O hydrogen bonds help to stabilize the crystal packing. The structure has already been published [Whitlow & Davey (1975 ▶). J. Chem. Soc. Dalton. Trans. pp. 1228–1232]; this redetermination reports the structure with higher precision. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915090/ /pubmed/21200501 http://dx.doi.org/10.1107/S1600536807065725 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Guo, Ming-Lin
Redetermination of poly[aquadi-μ(3)-oxy­diacetato-dicopper(II)]
title Redetermination of poly[aquadi-μ(3)-oxy­diacetato-dicopper(II)]
title_full Redetermination of poly[aquadi-μ(3)-oxy­diacetato-dicopper(II)]
title_fullStr Redetermination of poly[aquadi-μ(3)-oxy­diacetato-dicopper(II)]
title_full_unstemmed Redetermination of poly[aquadi-μ(3)-oxy­diacetato-dicopper(II)]
title_short Redetermination of poly[aquadi-μ(3)-oxy­diacetato-dicopper(II)]
title_sort redetermination of poly[aquadi-μ(3)-oxy­diacetato-dicopper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915090/
https://www.ncbi.nlm.nih.gov/pubmed/21200501
http://dx.doi.org/10.1107/S1600536807065725
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