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Redetermination of poly[aquadi-μ(3)-oxydiacetato-dicopper(II)]
The title complex, [Cu(2)(C(4)H(4)O(5))(2)(H(2)O)](n), has a two-dimensional layer structure. The Cu atom has a distorted octahedral (CuO(6)) environment and is coordinated by four carboxylate group O atoms from three different oxydiacetate ligands in a planar arrangement and one half-occupancy wa...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2007
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915090/ https://www.ncbi.nlm.nih.gov/pubmed/21200501 http://dx.doi.org/10.1107/S1600536807065725 |
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author | Guo, Ming-Lin |
author_facet | Guo, Ming-Lin |
author_sort | Guo, Ming-Lin |
collection | PubMed |
description | The title complex, [Cu(2)(C(4)H(4)O(5))(2)(H(2)O)](n), has a two-dimensional layer structure. The Cu atom has a distorted octahedral (CuO(6)) environment and is coordinated by four carboxylate group O atoms from three different oxydiacetate ligands in a planar arrangement and one half-occupancy water molecule and an ether O atom in the axial positions. In the crystal structure, weak intra- and intermolecular O—H⋯O hydrogen bonds help to stabilize the crystal packing. The structure has already been published [Whitlow & Davey (1975 ▶). J. Chem. Soc. Dalton. Trans. pp. 1228–1232]; this redetermination reports the structure with higher precision. |
format | Text |
id | pubmed-2915090 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29150902010-12-30 Redetermination of poly[aquadi-μ(3)-oxydiacetato-dicopper(II)] Guo, Ming-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(2)(C(4)H(4)O(5))(2)(H(2)O)](n), has a two-dimensional layer structure. The Cu atom has a distorted octahedral (CuO(6)) environment and is coordinated by four carboxylate group O atoms from three different oxydiacetate ligands in a planar arrangement and one half-occupancy water molecule and an ether O atom in the axial positions. In the crystal structure, weak intra- and intermolecular O—H⋯O hydrogen bonds help to stabilize the crystal packing. The structure has already been published [Whitlow & Davey (1975 ▶). J. Chem. Soc. Dalton. Trans. pp. 1228–1232]; this redetermination reports the structure with higher precision. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915090/ /pubmed/21200501 http://dx.doi.org/10.1107/S1600536807065725 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Guo, Ming-Lin Redetermination of poly[aquadi-μ(3)-oxydiacetato-dicopper(II)] |
title | Redetermination of poly[aquadi-μ(3)-oxydiacetato-dicopper(II)] |
title_full | Redetermination of poly[aquadi-μ(3)-oxydiacetato-dicopper(II)] |
title_fullStr | Redetermination of poly[aquadi-μ(3)-oxydiacetato-dicopper(II)] |
title_full_unstemmed | Redetermination of poly[aquadi-μ(3)-oxydiacetato-dicopper(II)] |
title_short | Redetermination of poly[aquadi-μ(3)-oxydiacetato-dicopper(II)] |
title_sort | redetermination of poly[aquadi-μ(3)-oxydiacetato-dicopper(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915090/ https://www.ncbi.nlm.nih.gov/pubmed/21200501 http://dx.doi.org/10.1107/S1600536807065725 |
work_keys_str_mv | AT guominglin redeterminationofpolyaquadim3oxydiacetatodicopperii |