Bis(tetra­phenyl­phospho­nium) bis­[N-(octyl­sulfon­yl)dithio­carbimato(2–)-κ(2) S,S′]­nickelate(II)

The Ni atom in the title complex, (C(24)H(20)P)(2)[Ni(C(9)H(17)NO(2)S(3))(2)], lies on a twofold axis within a square-planar geometry defined by four S atoms derived from two dithio­carbimate dianions, each forming a four-membered chelate ring. A small distortion, described by a deviation of the Ni(...

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Detalles Bibliográficos
Autores principales: Cunha, Leandro M. G., Rubinger, Mayura M. M., Oliveira, Marcelo R. L., Sabino, Jose R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915091/
https://www.ncbi.nlm.nih.gov/pubmed/21200502
http://dx.doi.org/10.1107/S1600536807065014
Descripción
Sumario:The Ni atom in the title complex, (C(24)H(20)P)(2)[Ni(C(9)H(17)NO(2)S(3))(2)], lies on a twofold axis within a square-planar geometry defined by four S atoms derived from two dithio­carbimate dianions, each forming a four-membered chelate ring. A small distortion, described by a deviation of the Ni(II) atom by 0.083 (1) Å from the plane through the four S atoms, and also by the torsion angles about the Ni—S bonds, implies a folded conformation for the chelate ring.

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