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Bis(tetraphenylphosphonium) bis[N-(octylsulfonyl)dithiocarbimato(2–)-κ(2) S,S′]nickelate(II)
The Ni atom in the title complex, (C(24)H(20)P)(2)[Ni(C(9)H(17)NO(2)S(3))(2)], lies on a twofold axis within a square-planar geometry defined by four S atoms derived from two dithiocarbimate dianions, each forming a four-membered chelate ring. A small distortion, described by a deviation of the Ni(...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2007
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915091/ https://www.ncbi.nlm.nih.gov/pubmed/21200502 http://dx.doi.org/10.1107/S1600536807065014 |
| _version_ | 1782184857879707648 |
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| author | Cunha, Leandro M. G. Rubinger, Mayura M. M. Oliveira, Marcelo R. L. Sabino, Jose R. |
| author_facet | Cunha, Leandro M. G. Rubinger, Mayura M. M. Oliveira, Marcelo R. L. Sabino, Jose R. |
| author_sort | Cunha, Leandro M. G. |
| collection | PubMed |
| description | The Ni atom in the title complex, (C(24)H(20)P)(2)[Ni(C(9)H(17)NO(2)S(3))(2)], lies on a twofold axis within a square-planar geometry defined by four S atoms derived from two dithiocarbimate dianions, each forming a four-membered chelate ring. A small distortion, described by a deviation of the Ni(II) atom by 0.083 (1) Å from the plane through the four S atoms, and also by the torsion angles about the Ni—S bonds, implies a folded conformation for the chelate ring. |
| format | Text |
| id | pubmed-2915091 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2007 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29150912010-12-30 Bis(tetraphenylphosphonium) bis[N-(octylsulfonyl)dithiocarbimato(2–)-κ(2) S,S′]nickelate(II) Cunha, Leandro M. G. Rubinger, Mayura M. M. Oliveira, Marcelo R. L. Sabino, Jose R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ni atom in the title complex, (C(24)H(20)P)(2)[Ni(C(9)H(17)NO(2)S(3))(2)], lies on a twofold axis within a square-planar geometry defined by four S atoms derived from two dithiocarbimate dianions, each forming a four-membered chelate ring. A small distortion, described by a deviation of the Ni(II) atom by 0.083 (1) Å from the plane through the four S atoms, and also by the torsion angles about the Ni—S bonds, implies a folded conformation for the chelate ring. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915091/ /pubmed/21200502 http://dx.doi.org/10.1107/S1600536807065014 Text en © Cunha et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Cunha, Leandro M. G. Rubinger, Mayura M. M. Oliveira, Marcelo R. L. Sabino, Jose R. Bis(tetraphenylphosphonium) bis[N-(octylsulfonyl)dithiocarbimato(2–)-κ(2) S,S′]nickelate(II) |
| title | Bis(tetraphenylphosphonium) bis[N-(octylsulfonyl)dithiocarbimato(2–)-κ(2)
S,S′]nickelate(II) |
| title_full | Bis(tetraphenylphosphonium) bis[N-(octylsulfonyl)dithiocarbimato(2–)-κ(2)
S,S′]nickelate(II) |
| title_fullStr | Bis(tetraphenylphosphonium) bis[N-(octylsulfonyl)dithiocarbimato(2–)-κ(2)
S,S′]nickelate(II) |
| title_full_unstemmed | Bis(tetraphenylphosphonium) bis[N-(octylsulfonyl)dithiocarbimato(2–)-κ(2)
S,S′]nickelate(II) |
| title_short | Bis(tetraphenylphosphonium) bis[N-(octylsulfonyl)dithiocarbimato(2–)-κ(2)
S,S′]nickelate(II) |
| title_sort | bis(tetraphenylphosphonium) bis[n-(octylsulfonyl)dithiocarbimato(2–)-κ(2)
s,s′]nickelate(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915091/ https://www.ncbi.nlm.nih.gov/pubmed/21200502 http://dx.doi.org/10.1107/S1600536807065014 |
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