catena-Poly[[[bis­(4-amino­benzoato-κO)copper(II)]-μ-1,1′-(pentane-1,5-di­yl)diimidazole] trihydrate]

In the title compound, {[Cu(C(7)H(6)NO(2))(2)(C(11)H(16)N(4))]·3H(2)O}(n), each Cu(II) atom is coordinated by two O atoms from two 4-amino­benzoate anions, and two N atoms from two different 1,1′-(pentane-1,5-di­yl)diimidazole (biim-5) ligands, to furnish a distorted square-planar geometry. The biim...

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Detalles Bibliográficos
Autores principales: Zhang, Wen-Li, Zhang, Lai-Ping, Ma, Jian-Fang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915095/
https://www.ncbi.nlm.nih.gov/pubmed/21200507
http://dx.doi.org/10.1107/S1600536807064586
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author Zhang, Wen-Li
Zhang, Lai-Ping
Ma, Jian-Fang
author_facet Zhang, Wen-Li
Zhang, Lai-Ping
Ma, Jian-Fang
author_sort Zhang, Wen-Li
collection PubMed
description In the title compound, {[Cu(C(7)H(6)NO(2))(2)(C(11)H(16)N(4))]·3H(2)O}(n), each Cu(II) atom is coordinated by two O atoms from two 4-amino­benzoate anions, and two N atoms from two different 1,1′-(pentane-1,5-di­yl)diimidazole (biim-5) ligands, to furnish a distorted square-planar geometry. The biim-5 ligand coordinates to two copper(II) cations, acting as a bridging ligand; as a result the copper(II) cations are connected to form an infinite chain structure. The polymeric chains are linked through a variety of hydrogen bonds to form a three-dimensional structure.
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spelling pubmed-29150952010-12-30 catena-Poly[[[bis­(4-amino­benzoato-κO)copper(II)]-μ-1,1′-(pentane-1,5-di­yl)diimidazole] trihydrate] Zhang, Wen-Li Zhang, Lai-Ping Ma, Jian-Fang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Cu(C(7)H(6)NO(2))(2)(C(11)H(16)N(4))]·3H(2)O}(n), each Cu(II) atom is coordinated by two O atoms from two 4-amino­benzoate anions, and two N atoms from two different 1,1′-(pentane-1,5-di­yl)diimidazole (biim-5) ligands, to furnish a distorted square-planar geometry. The biim-5 ligand coordinates to two copper(II) cations, acting as a bridging ligand; as a result the copper(II) cations are connected to form an infinite chain structure. The polymeric chains are linked through a variety of hydrogen bonds to form a three-dimensional structure. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915095/ /pubmed/21200507 http://dx.doi.org/10.1107/S1600536807064586 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Zhang, Wen-Li
Zhang, Lai-Ping
Ma, Jian-Fang
catena-Poly[[[bis­(4-amino­benzoato-κO)copper(II)]-μ-1,1′-(pentane-1,5-di­yl)diimidazole] trihydrate]
title catena-Poly[[[bis­(4-amino­benzoato-κO)copper(II)]-μ-1,1′-(pentane-1,5-di­yl)diimidazole] trihydrate]
title_full catena-Poly[[[bis­(4-amino­benzoato-κO)copper(II)]-μ-1,1′-(pentane-1,5-di­yl)diimidazole] trihydrate]
title_fullStr catena-Poly[[[bis­(4-amino­benzoato-κO)copper(II)]-μ-1,1′-(pentane-1,5-di­yl)diimidazole] trihydrate]
title_full_unstemmed catena-Poly[[[bis­(4-amino­benzoato-κO)copper(II)]-μ-1,1′-(pentane-1,5-di­yl)diimidazole] trihydrate]
title_short catena-Poly[[[bis­(4-amino­benzoato-κO)copper(II)]-μ-1,1′-(pentane-1,5-di­yl)diimidazole] trihydrate]
title_sort catena-poly[[[bis­(4-amino­benzoato-κo)copper(ii)]-μ-1,1′-(pentane-1,5-di­yl)diimidazole] trihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915095/
https://www.ncbi.nlm.nih.gov/pubmed/21200507
http://dx.doi.org/10.1107/S1600536807064586
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AT majianfang catenapolybis4aminobenzoatokocopperiim11pentane15diyldiimidazoletrihydrate

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