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Tetrakis(μ-phenoxyacetato-κ(2) O:O′)bis[(1,10-phenanthroline-κ(2) N,N′)manganese(II)] methanol hemisolvate
The title complex, [Mn(2)(C(8)H(7)O(3))(4)(C(12)H(8)N(2))(2)]·0.5CH(3)OH, is a carboxylate-bridged dinuclear Mn(II) complex with four phenoxyacetate ions and two 1,10-phenanthroline molecules as ligands. Each of the four phenoxyacetate anions bridges the pair of Mn atoms. The asymmetric unit is...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2007
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915099/ https://www.ncbi.nlm.nih.gov/pubmed/21200511 http://dx.doi.org/10.1107/S1600536807065269 |
| _version_ | 1782184859778678784 |
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| author | Wu, Dong-Hui Shi, Jian Shi, Yu-Jun Jiang, Guo-Qing |
| author_facet | Wu, Dong-Hui Shi, Jian Shi, Yu-Jun Jiang, Guo-Qing |
| author_sort | Wu, Dong-Hui |
| collection | PubMed |
| description | The title complex, [Mn(2)(C(8)H(7)O(3))(4)(C(12)H(8)N(2))(2)]·0.5CH(3)OH, is a carboxylate-bridged dinuclear Mn(II) complex with four phenoxyacetate ions and two 1,10-phenanthroline molecules as ligands. Each of the four phenoxyacetate anions bridges the pair of Mn atoms. The asymmetric unit is completed by a half-occupancy methanol solvent molecule. Face-to-face π–π stacking interactions between the aromatic rings of 1,10-phenanthroline molecules belonging to adjacent Mn(2) complexes, with an interplanar separation of circa 3.4 Å, and weak C—H⋯O hydrogen bonds connect the dinuclear units into a three-dimensional supramolecular framework. |
| format | Text |
| id | pubmed-2915099 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2007 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29150992010-12-30 Tetrakis(μ-phenoxyacetato-κ(2) O:O′)bis[(1,10-phenanthroline-κ(2) N,N′)manganese(II)] methanol hemisolvate Wu, Dong-Hui Shi, Jian Shi, Yu-Jun Jiang, Guo-Qing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Mn(2)(C(8)H(7)O(3))(4)(C(12)H(8)N(2))(2)]·0.5CH(3)OH, is a carboxylate-bridged dinuclear Mn(II) complex with four phenoxyacetate ions and two 1,10-phenanthroline molecules as ligands. Each of the four phenoxyacetate anions bridges the pair of Mn atoms. The asymmetric unit is completed by a half-occupancy methanol solvent molecule. Face-to-face π–π stacking interactions between the aromatic rings of 1,10-phenanthroline molecules belonging to adjacent Mn(2) complexes, with an interplanar separation of circa 3.4 Å, and weak C—H⋯O hydrogen bonds connect the dinuclear units into a three-dimensional supramolecular framework. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915099/ /pubmed/21200511 http://dx.doi.org/10.1107/S1600536807065269 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
| spellingShingle | Metal-Organic Papers Wu, Dong-Hui Shi, Jian Shi, Yu-Jun Jiang, Guo-Qing Tetrakis(μ-phenoxyacetato-κ(2) O:O′)bis[(1,10-phenanthroline-κ(2) N,N′)manganese(II)] methanol hemisolvate |
| title | Tetrakis(μ-phenoxyacetato-κ(2)
O:O′)bis[(1,10-phenanthroline-κ(2)
N,N′)manganese(II)] methanol hemisolvate |
| title_full | Tetrakis(μ-phenoxyacetato-κ(2)
O:O′)bis[(1,10-phenanthroline-κ(2)
N,N′)manganese(II)] methanol hemisolvate |
| title_fullStr | Tetrakis(μ-phenoxyacetato-κ(2)
O:O′)bis[(1,10-phenanthroline-κ(2)
N,N′)manganese(II)] methanol hemisolvate |
| title_full_unstemmed | Tetrakis(μ-phenoxyacetato-κ(2)
O:O′)bis[(1,10-phenanthroline-κ(2)
N,N′)manganese(II)] methanol hemisolvate |
| title_short | Tetrakis(μ-phenoxyacetato-κ(2)
O:O′)bis[(1,10-phenanthroline-κ(2)
N,N′)manganese(II)] methanol hemisolvate |
| title_sort | tetrakis(μ-phenoxyacetato-κ(2)
o:o′)bis[(1,10-phenanthroline-κ(2)
n,n′)manganese(ii)] methanol hemisolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915099/ https://www.ncbi.nlm.nih.gov/pubmed/21200511 http://dx.doi.org/10.1107/S1600536807065269 |
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