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The one-dimensional polymer poly[[aqua­(2,2′-bipyridine)cadmium(II)]-μ-trans-stilbene-4,4′-dicarboxyl­ato]

In the title polymer, [Cd(C(16)H(10)O(4))(C(10)H(8)N(2))(H(2)O)](n), the Cd(II) ion is in a strongly distorted octa­hedral geometry, being coordinated by two N atoms from a 2,2′-bipyridine ligand, three carboxylate O atoms from two symmetry-related trans-stilbene-4,4′-dicarboxyl­ate dianions and one...

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Detalles Bibliográficos
Autores principales: Wang, Huan-Yu, Gao, Shan, Huo, Li-Hua, Zhao, Jing-Gui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2007
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915100/
https://www.ncbi.nlm.nih.gov/pubmed/21200512
http://dx.doi.org/10.1107/S1600536807065294
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author Wang, Huan-Yu
Gao, Shan
Huo, Li-Hua
Zhao, Jing-Gui
author_facet Wang, Huan-Yu
Gao, Shan
Huo, Li-Hua
Zhao, Jing-Gui
author_sort Wang, Huan-Yu
collection PubMed
description In the title polymer, [Cd(C(16)H(10)O(4))(C(10)H(8)N(2))(H(2)O)](n), the Cd(II) ion is in a strongly distorted octa­hedral geometry, being coordinated by two N atoms from a 2,2′-bipyridine ligand, three carboxylate O atoms from two symmetry-related trans-stilbene-4,4′-dicarboxyl­ate dianions and one water mol­ecule. The stilbene ligand lies on an inversion centre at the midpoint of the central C=C bond. This feature generates the polymeric structure: adjacent Cd(II) ions are bridged by trans-stilbene-4,4′-dicarboxyl­ate dianions, giving rise to a one-dimensional structure. The coordinated water mol­ecule is involved in interchain O—H⋯O hydrogen bonds.
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spelling pubmed-29151002010-12-30 The one-dimensional polymer poly[[aqua­(2,2′-bipyridine)cadmium(II)]-μ-trans-stilbene-4,4′-dicarboxyl­ato] Wang, Huan-Yu Gao, Shan Huo, Li-Hua Zhao, Jing-Gui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymer, [Cd(C(16)H(10)O(4))(C(10)H(8)N(2))(H(2)O)](n), the Cd(II) ion is in a strongly distorted octa­hedral geometry, being coordinated by two N atoms from a 2,2′-bipyridine ligand, three carboxylate O atoms from two symmetry-related trans-stilbene-4,4′-dicarboxyl­ate dianions and one water mol­ecule. The stilbene ligand lies on an inversion centre at the midpoint of the central C=C bond. This feature generates the polymeric structure: adjacent Cd(II) ions are bridged by trans-stilbene-4,4′-dicarboxyl­ate dianions, giving rise to a one-dimensional structure. The coordinated water mol­ecule is involved in interchain O—H⋯O hydrogen bonds. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915100/ /pubmed/21200512 http://dx.doi.org/10.1107/S1600536807065294 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Wang, Huan-Yu
Gao, Shan
Huo, Li-Hua
Zhao, Jing-Gui
The one-dimensional polymer poly[[aqua­(2,2′-bipyridine)cadmium(II)]-μ-trans-stilbene-4,4′-dicarboxyl­ato]
title The one-dimensional polymer poly[[aqua­(2,2′-bipyridine)cadmium(II)]-μ-trans-stilbene-4,4′-dicarboxyl­ato]
title_full The one-dimensional polymer poly[[aqua­(2,2′-bipyridine)cadmium(II)]-μ-trans-stilbene-4,4′-dicarboxyl­ato]
title_fullStr The one-dimensional polymer poly[[aqua­(2,2′-bipyridine)cadmium(II)]-μ-trans-stilbene-4,4′-dicarboxyl­ato]
title_full_unstemmed The one-dimensional polymer poly[[aqua­(2,2′-bipyridine)cadmium(II)]-μ-trans-stilbene-4,4′-dicarboxyl­ato]
title_short The one-dimensional polymer poly[[aqua­(2,2′-bipyridine)cadmium(II)]-μ-trans-stilbene-4,4′-dicarboxyl­ato]
title_sort one-dimensional polymer poly[[aqua­(2,2′-bipyridine)cadmium(ii)]-μ-trans-stilbene-4,4′-dicarboxyl­ato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915100/
https://www.ncbi.nlm.nih.gov/pubmed/21200512
http://dx.doi.org/10.1107/S1600536807065294
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