Cargando…
The one-dimensional polymer poly[[aqua(2,2′-bipyridine)cadmium(II)]-μ-trans-stilbene-4,4′-dicarboxylato]
In the title polymer, [Cd(C(16)H(10)O(4))(C(10)H(8)N(2))(H(2)O)](n), the Cd(II) ion is in a strongly distorted octahedral geometry, being coordinated by two N atoms from a 2,2′-bipyridine ligand, three carboxylate O atoms from two symmetry-related trans-stilbene-4,4′-dicarboxylate dianions and one...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2007
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915100/ https://www.ncbi.nlm.nih.gov/pubmed/21200512 http://dx.doi.org/10.1107/S1600536807065294 |
_version_ | 1782184860021948416 |
---|---|
author | Wang, Huan-Yu Gao, Shan Huo, Li-Hua Zhao, Jing-Gui |
author_facet | Wang, Huan-Yu Gao, Shan Huo, Li-Hua Zhao, Jing-Gui |
author_sort | Wang, Huan-Yu |
collection | PubMed |
description | In the title polymer, [Cd(C(16)H(10)O(4))(C(10)H(8)N(2))(H(2)O)](n), the Cd(II) ion is in a strongly distorted octahedral geometry, being coordinated by two N atoms from a 2,2′-bipyridine ligand, three carboxylate O atoms from two symmetry-related trans-stilbene-4,4′-dicarboxylate dianions and one water molecule. The stilbene ligand lies on an inversion centre at the midpoint of the central C=C bond. This feature generates the polymeric structure: adjacent Cd(II) ions are bridged by trans-stilbene-4,4′-dicarboxylate dianions, giving rise to a one-dimensional structure. The coordinated water molecule is involved in interchain O—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2915100 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2007 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29151002010-12-30 The one-dimensional polymer poly[[aqua(2,2′-bipyridine)cadmium(II)]-μ-trans-stilbene-4,4′-dicarboxylato] Wang, Huan-Yu Gao, Shan Huo, Li-Hua Zhao, Jing-Gui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymer, [Cd(C(16)H(10)O(4))(C(10)H(8)N(2))(H(2)O)](n), the Cd(II) ion is in a strongly distorted octahedral geometry, being coordinated by two N atoms from a 2,2′-bipyridine ligand, three carboxylate O atoms from two symmetry-related trans-stilbene-4,4′-dicarboxylate dianions and one water molecule. The stilbene ligand lies on an inversion centre at the midpoint of the central C=C bond. This feature generates the polymeric structure: adjacent Cd(II) ions are bridged by trans-stilbene-4,4′-dicarboxylate dianions, giving rise to a one-dimensional structure. The coordinated water molecule is involved in interchain O—H⋯O hydrogen bonds. International Union of Crystallography 2007-12-12 /pmc/articles/PMC2915100/ /pubmed/21200512 http://dx.doi.org/10.1107/S1600536807065294 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Wang, Huan-Yu Gao, Shan Huo, Li-Hua Zhao, Jing-Gui The one-dimensional polymer poly[[aqua(2,2′-bipyridine)cadmium(II)]-μ-trans-stilbene-4,4′-dicarboxylato] |
title | The one-dimensional polymer poly[[aqua(2,2′-bipyridine)cadmium(II)]-μ-trans-stilbene-4,4′-dicarboxylato] |
title_full | The one-dimensional polymer poly[[aqua(2,2′-bipyridine)cadmium(II)]-μ-trans-stilbene-4,4′-dicarboxylato] |
title_fullStr | The one-dimensional polymer poly[[aqua(2,2′-bipyridine)cadmium(II)]-μ-trans-stilbene-4,4′-dicarboxylato] |
title_full_unstemmed | The one-dimensional polymer poly[[aqua(2,2′-bipyridine)cadmium(II)]-μ-trans-stilbene-4,4′-dicarboxylato] |
title_short | The one-dimensional polymer poly[[aqua(2,2′-bipyridine)cadmium(II)]-μ-trans-stilbene-4,4′-dicarboxylato] |
title_sort | one-dimensional polymer poly[[aqua(2,2′-bipyridine)cadmium(ii)]-μ-trans-stilbene-4,4′-dicarboxylato] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2915100/ https://www.ncbi.nlm.nih.gov/pubmed/21200512 http://dx.doi.org/10.1107/S1600536807065294 |
work_keys_str_mv | AT wanghuanyu theonedimensionalpolymerpolyaqua22bipyridinecadmiumiimtransstilbene44dicarboxylato AT gaoshan theonedimensionalpolymerpolyaqua22bipyridinecadmiumiimtransstilbene44dicarboxylato AT huolihua theonedimensionalpolymerpolyaqua22bipyridinecadmiumiimtransstilbene44dicarboxylato AT zhaojinggui theonedimensionalpolymerpolyaqua22bipyridinecadmiumiimtransstilbene44dicarboxylato AT wanghuanyu onedimensionalpolymerpolyaqua22bipyridinecadmiumiimtransstilbene44dicarboxylato AT gaoshan onedimensionalpolymerpolyaqua22bipyridinecadmiumiimtransstilbene44dicarboxylato AT huolihua onedimensionalpolymerpolyaqua22bipyridinecadmiumiimtransstilbene44dicarboxylato AT zhaojinggui onedimensionalpolymerpolyaqua22bipyridinecadmiumiimtransstilbene44dicarboxylato |